PMID- 31500273 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201001 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 9 IP - 9 DP - 2019 Sep 7 TI - Synthesis of ZnO Hierarchical Structures and Their Gas Sensing Properties. LID - 10.3390/nano9091277 [doi] LID - 1277 AB - Firecracker-like ZnO hierarchical structures (ZnO HS1) were synthesized by combining electrospinning with hydrothermal methods. Flower-like ZnO hierarchical structures (ZnO HS2) were prepared by a hydrothermal method using ultrasound-treated ZnO nanofibers (ZnO NFs) as raw material which has rarely been reported in previous papers. Scanning electron microscope (SEM) and transmission electron microscope's (TEM) images clearly indicated the existence of nanoparticles on the ZnO HS2 material. Both gas sensors exhibited high selectivity toward H(2)S gas over various other gases at 180 degrees C. The ZnO HS2 gas sensor exhibited higher H(2)S sensitivity response (50 ppm H(2)S, 42.298) at 180 degrees C than ZnO NFs (50 ppm H(2)S, 9.223) and ZnO HS1 (50 ppm H(2)S, 17.506) gas sensors. Besides, the ZnO HS2 sensor showed a shorter response time (14 s) compared with the ZnO NFs (25 s) and ZnO HS1 (19 s) gas sensors. The formation diagram of ZnO hierarchical structures and the gas sensing mechanism were evaluated. Apart from the synergistic effect of nanoparticles and nanoflowers, more point-point contacts between flower-like ZnO nanorods were advantageous for the excellent H(2)S sensing properties of ZnO HS2 material. FAU - Fan, Chao AU - Fan C AD - Laboratory of Functional Molecular and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. fc17509190@outlook.com. AD - School of Material Science and Engineering, Shandong University of Technology, Zibo 255000, China. fc17509190@outlook.com. FAU - Sun, Fazhe AU - Sun F AD - Analysis and Testing Center, Shandong University of Technology, Zibo 255000, China. fazhesun@163.com. FAU - Wang, Xiaomei AU - Wang X AD - Laboratory of Functional Molecular and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. xiaomeiwang@sdut.edu.cn. FAU - Huang, Zuzhen AU - Huang Z AD - Laboratory of Functional Molecular and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. zuzhen_huang@163.com. FAU - Keshvardoostchokami, Mina AU - Keshvardoostchokami M AD - Laboratory of Functional Molecular and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. minak@sdut.edu.cn. FAU - Kumar, Parveen AU - Kumar P AUID- ORCID: 0000-0001-5566-2843 AD - Laboratory of Functional Molecular and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. kumar@sdut.edu.cn. FAU - Liu, Bo AU - Liu B AD - Laboratory of Functional Molecular and Materials, School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo 255000, China. liub@sdut.edu.cn. AD - School of Material Science and Engineering, Shandong University of Technology, Zibo 255000, China. liub@sdut.edu.cn. LA - eng GR - 61704098/National Natural Science Foundation of China/ GR - ZR2017BF025/Natural Science Foundation of Shandong Province/ PT - Journal Article DEP - 20190907 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC6781051 OTO - NOTNLM OT - H2S OT - electrospinning OT - gas sensing OT - hierarchical structures OT - hydrothermal COIS- The authors declare no conflict of interest. EDAT- 2019/09/11 06:00 MHDA- 2019/09/11 06:01 PMCR- 2019/09/07 CRDT- 2019/09/11 06:00 PHST- 2019/08/13 00:00 [received] PHST- 2019/08/25 00:00 [revised] PHST- 2019/09/04 00:00 [accepted] PHST- 2019/09/11 06:00 [entrez] PHST- 2019/09/11 06:00 [pubmed] PHST- 2019/09/11 06:01 [medline] PHST- 2019/09/07 00:00 [pmc-release] AID - nano9091277 [pii] AID - nanomaterials-09-01277 [pii] AID - 10.3390/nano9091277 [doi] PST - epublish SO - Nanomaterials (Basel). 2019 Sep 7;9(9):1277. doi: 10.3390/nano9091277.