PMID- 31509392
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20191015
LR  - 20200706
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 58
IP  - 19
DP  - 2019 Oct 7
TI  - NH(2)-MIL-53(Al) Metal-Organic Framework as the Smart Platform for Simultaneous 
      High-Performance Detection and Removal of Hg(2).
PG  - 12573-12581
LID - 10.1021/acs.inorgchem.9b01242 [doi]
AB  - The worsening pollution due to mercury species makes it inevitable to explore 
      prospective versatile materials, which not only can detect mercury ions (Hg(2+)) 
      with high sensitivity but also possesses efficient capture and removal ability. 
      In this study, a series of classic organic ligand-based luminescence MOFs 
      materials with high oxidation state central metals (Al(3+), Zr(4+), Cr(3+), 
      Fe(3+), and Ti(4+)) were synthesized and were screened to achieve simultaneously 
      Hg(2+) detection and removal through the strong coordination of amino groups or 
      nitrogen centers with Hg(2+) and the intrinsic fluorescence intensity of MOFs 
      regulated by the ligand-to-metal charge transfer (LMCT) effect. Among these 
      checked materials, NH(2)-MIL-53(Al) exhibited the excellent ability for Hg(2+) 
      detection with wide response interval (1-17.3 muM), low detection limit (0.15 muM), 
      good selectivity, wide pH adaptation (4.0-10.0), and strong anti-interference 
      ability. Meanwhile, the resultant NH(2)-MIL-53(Al) possessed an efficient removal 
      capability toward Hg(2+), accompanied by a fast uptake kinetics (within 60 min) 
      and large loading capacity (153.85 mg g(-1)). Furthermore, NH(2)-MIL-53(Al) also 
      displayed satisfactory stability before and after Hg(2+) treatment because of the 
      formation of strong coordination bonds between high oxidation state aluminum 
      (Al(3+)) and organic carboxylate ligands. Notably, the prepared NH(2)-MIL-53(Al) 
      had no significant loss of adsorption performance even after being reused four 
      times. All of these superior properties render the smart NH(2)-MIL-53(Al) 
      nanohexahedron a great potential for simultaneous Hg(2+) detection and removal 
      from water.
FAU - Zhang, Liang
AU  - Zhang L
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Wang, Jing
AU  - Wang J
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Du, Ting
AU  - Du T
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Zhang, Wentao
AU  - Zhang W
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Zhu, Wenxin
AU  - Zhu W
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Yang, Chengyuan
AU  - Yang C
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Yue, Tianli
AU  - Yue T
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
FAU - Sun, Jing
AU  - Sun J
AD  - Qinghai Provincial Key Laboratory of Qinghai-Tibet Plateau Biological Resources, 
      Northwest Institute of Plateau Biology , Chinese Academy of Sciences , 23 Xinning 
      Road , Xining 810008 , Qinghai , China.
FAU - Li, Tao
AU  - Li T
AD  - Shaanxi Institute for Food and Drug Control , Xi'an 710065 , China.
FAU - Wang, Jianlong
AU  - Wang J
AUID- ORCID: 0000-0002-2879-9489
AD  - College of Food Science and Engineering , Northwest A&F University , 22 Xinong 
      Road , Yangling 712100 , Shaanxi , China.
LA  - eng
PT  - Journal Article
DEP - 20190911
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
SB  - IM
EIN - Inorg Chem. 2020 Jul 20;59(14):10375-10376. PMID: 32618469
EDAT- 2019/09/12 06:00
MHDA- 2019/09/12 06:01
CRDT- 2019/09/12 06:00
PHST- 2019/09/12 06:00 [pubmed]
PHST- 2019/09/12 06:01 [medline]
PHST- 2019/09/12 06:00 [entrez]
AID - 10.1021/acs.inorgchem.9b01242 [doi]
PST - ppublish
SO  - Inorg Chem. 2019 Oct 7;58(19):12573-12581. doi: 10.1021/acs.inorgchem.9b01242. 
      Epub 2019 Sep 11.