PMID- 31514887
OWN - NLM
STAT- MEDLINE
DCOM- 20200213
LR  - 20200213
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 206
DP  - 2020 Jan 1
TI  - Enrichment and sensitive determination of phthalate esters in environmental water 
      samples: A novel approach of MSPE-HPLC based on PAMAM dendrimers-functionalized 
      magnetic-nanoparticles.
PG  - 120213
LID - S0039-9140(19)30846-X [pii]
LID - 10.1016/j.talanta.2019.120213 [doi]
AB  - Phthalate esters (PAEs) are an important kind of environmental endocrine 
      disrupting chemicals, and have attracted great attention in environmental field. 
      Present study described a new method for rapid and sensitive determination of 
      PAEs including dibenzyl phthalate (DPhP), dibutyl phthalate (DnPP), and 
      dicyclohexyl phthalate (DCHP) from aqueous matrices based on magnetic solid-phase 
      extraction. Polyamidoamine (PAMAM) dendrimers-grafted magnetic-nanoparticles were 
      synthesized and characterized, and the expected integration of more 
      multifunctional sites of PAMAM dendrimers and rapid separation property was 
      utilized for method development. To achieve the best extraction efficiency, 
      several important parameters were optimized including the dosage of the 
      adsorbent, sample pH, kind and volume of eluent, extraction time, desorption 
      time, ionic strength. Under the optimal conditions, three phthalate esters were 
      well enriched and simultaneously determined by high performance liquid 
      chromatography with variable wavelength detector (VWD). Excellent linearities 
      were observed in the range of 0.1-600 mug L(-1) for DPhP and DnPP and 
      0.5-600 mug L(-1) for DCHP, and all correlation coefficients (R(2)) were larger 
      than 0.997. The limits of detection (LODs, S/N = 3) were ranged from 0.025 to 
      0.16 mug L(-1). The spiked recoveries of PAEs in real water samples were in the 
      range of 93.5-101.8% with satisfied relative standard deviations (RSDs) ranging 
      from 0.9 to 4.1%. The prepared magnetic materials have shown good adsorption 
      capability for PAEs and the developed method earned merits such as high 
      sensitivity, simplicity, rapidness and environmental friendliness, which can be 
      used as a robust alternative tool for monitoring PAEs in water samples.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Wu, Yalin
AU  - Wu Y
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
FAU - Zhou, Qingxiang
AU  - Zhou Q
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China. Electronic address: zhouqx@cup.edu.cn.
FAU - Yuan, Yongyong
AU  - Yuan Y
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
FAU - Wang, Hongyuan
AU  - Wang H
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
FAU - Tong, Yayan
AU  - Tong Y
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
FAU - Zhan, Yali
AU  - Zhan Y
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China. Electronic address: yalizhan1970@163.com.
FAU - Sheng, Xueying
AU  - Sheng X
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
FAU - Sun, Yi
AU  - Sun Y
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
FAU - Zhou, Xianqi
AU  - Zhou X
AD  - State Key Laboratory of Heavy Oil Processing, State Key Laboratory of Petroleum 
      Pollution Control, China University of Petroleum (Beijing), Beijing, 102249, 
      China.
LA  - eng
PT  - Journal Article
DEP - 20190801
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Dendrimers)
RN  - 0 (Esters)
RN  - 0 (Magnetite Nanoparticles)
RN  - 0 (Phthalic Acids)
RN  - 0 (Water Pollutants, Chemical)
RN  - 2286E5R2KE (Dibutyl Phthalate)
RN  - CGD15M7H2N (dicyclohexyl phthalate)
SB  - IM
MH  - Chromatography, High Pressure Liquid/methods
MH  - Dendrimers/*chemistry
MH  - Dibutyl Phthalate/analysis
MH  - Esters/*analysis
MH  - Lakes/analysis
MH  - Limit of Detection
MH  - Magnetite Nanoparticles/*chemistry
MH  - Oceans and Seas
MH  - Phthalic Acids/*analysis
MH  - Solid Phase Extraction/methods
MH  - Water Pollutants, Chemical/*analysis
OTO - NOTNLM
OT  - Environmental water samples
OT  - High performance liquid chromatography
OT  - Magnetic solid-phase extraction
OT  - PAMAM dendrimers
OT  - Phthalate esters
EDAT- 2019/09/14 06:00
MHDA- 2020/02/14 06:00
CRDT- 2019/09/14 06:00
PHST- 2019/05/13 00:00 [received]
PHST- 2019/07/21 00:00 [revised]
PHST- 2019/07/31 00:00 [accepted]
PHST- 2019/09/14 06:00 [entrez]
PHST- 2019/09/14 06:00 [pubmed]
PHST- 2020/02/14 06:00 [medline]
AID - S0039-9140(19)30846-X [pii]
AID - 10.1016/j.talanta.2019.120213 [doi]
PST - ppublish
SO  - Talanta. 2020 Jan 1;206:120213. doi: 10.1016/j.talanta.2019.120213. Epub 2019 Aug 
      1.