PMID- 31522125 OWN - NLM STAT- MEDLINE DCOM- 20200102 LR - 20200102 IS - 1873-7072 (Electronic) IS - 0308-8146 (Linking) VI - 305 DP - 2020 Feb 1 TI - Chemometric authentication of farming systems of origin of food (milk and ripened cheese) using infrared spectra, fatty acid profiles, flavor fingerprints, and sensory descriptions. PG - 125480 LID - S0308-8146(19)31597-3 [pii] LID - 10.1016/j.foodchem.2019.125480 [doi] AB - Milk samples from 1264 cows in 85 farms were authenticated for different farming-systems using a 10-fold cross-validated linear-discriminant-analysis using Fourier-transform infrared spectra (FTIRS) and gas-chromatographic fatty-acid (FA) profiles. FTIRS gave correct classification greater than FAs (97.4% vs. 81.1%) during calibration, but slightly worse in validation (73.5% vs 77.3%) and their combination improved the results. All milk samples were processed into ripened model-cheeses, and analyzed by near-infrared-spectrometry (NIRS), by proton-transfer-reaction time-of-flight mass-spectrometry for their volatile organic compound (VOCs) fingerprint and by panel sensory profiling (SENS). Farming-system authentication on cheese samples was less efficient than on milk, but still possible. The instrumental methods yielded similar validation results, better than SENS, and their combination improved the correct classification rate. The efficiency of the different technics was affected by specific farming systems. In conclusion, dairy products could be discriminated for farming-systems with acceptable accuracy, but the methods tested differ in sampling procedure, rapidity and costs. CI - Copyright (c) 2019 Elsevier Ltd. All rights reserved. FAU - Bergamaschi, Matteo AU - Bergamaschi M AD - Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, Viale dell'Universita 16, 35020 Legnaro, Padova, Italy. FAU - Cipolat-Gotet, Claudio AU - Cipolat-Gotet C AD - Department of Veterinary Science, University of Parma, Via del Taglio 10, 43126 Parma, Italy. FAU - Cecchinato, Alessio AU - Cecchinato A AD - Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, Viale dell'Universita 16, 35020 Legnaro, Padova, Italy. Electronic address: alessio.cecchinato@unipd.it. FAU - Schiavon, Stefano AU - Schiavon S AD - Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, Viale dell'Universita 16, 35020 Legnaro, Padova, Italy. FAU - Bittante, Giovanni AU - Bittante G AD - Department of Agronomy, Food, Natural Resources, Animals and Environment (DAFNAE), University of Padova, Viale dell'Universita 16, 35020 Legnaro, Padova, Italy. LA - eng PT - Journal Article DEP - 20190906 PL - England TA - Food Chem JT - Food chemistry JID - 7702639 RN - 0 (Fatty Acids) RN - 0 (Flavoring Agents) RN - 0 (Volatile Organic Compounds) SB - IM MH - Animals MH - Cattle MH - Cheese/*analysis MH - Chromatography, Gas MH - Discriminant Analysis MH - Fatty Acids/analysis/*chemistry MH - Female MH - Flavoring Agents/*analysis MH - Food Analysis MH - Mass Spectrometry MH - Milk/*chemistry MH - Spectroscopy, Fourier Transform Infrared MH - Volatile Organic Compounds/analysis OTO - NOTNLM OT - Food authentication OT - Food origin discrimination OT - Food quality monitoring, volatile organic compound OT - Silage feeding EDAT- 2019/09/16 06:00 MHDA- 2020/01/03 06:00 CRDT- 2019/09/16 06:00 PHST- 2019/03/11 00:00 [received] PHST- 2019/09/03 00:00 [revised] PHST- 2019/09/04 00:00 [accepted] PHST- 2019/09/16 06:00 [pubmed] PHST- 2020/01/03 06:00 [medline] PHST- 2019/09/16 06:00 [entrez] AID - S0308-8146(19)31597-3 [pii] AID - 10.1016/j.foodchem.2019.125480 [doi] PST - ppublish SO - Food Chem. 2020 Feb 1;305:125480. doi: 10.1016/j.foodchem.2019.125480. Epub 2019 Sep 6.