PMID- 31549761
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200413
LR  - 20200413
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 58
IP  - 48
DP  - 2019 Nov 25
TI  - The Ultrafast and Continuous Fabrication of a Polydimethylsiloxane Membrane by 
      Ultraviolet-Induced Polymerization.
PG  - 17175-17179
LID - 10.1002/anie.201908386 [doi]
AB  - The polydimethylsiloxane (PDMS) membrane commonly used for separation of 
      biobutanol from fermentation broth fails to meet demand owing to its 
      discontinuous and polluting thermal fabrication. Now, an UV-induced 
      polymerization strategy is proposed to realize the ultrafast and continuous 
      fabrication of the PDMS membrane. UV-crosslinking of synthesized 
      methacrylate-functionalized PDMS (MA-PDMS) is complete within 30 s. The 
      crosslinking rate is three orders of magnitude larger than the conventional 
      thermal crosslinking. The MA-PDMS membrane shows a versatile potential for liquid 
      and gas separations, especially featuring an excellent pervaporation performance 
      for n-butanol. Filler aggregation, the major bottleneck for the development of 
      high-performance mixed matrix membranes (MMMs), is overcome, because the UV 
      polymerization strategy demonstrates a freezing effect towards fillers in 
      polymer, resulting in an extremely high-loading silicalite-1/MA-PDMS MMM with 
      uniform particle distribution.
CI  - (c) 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Si, Zhihao
AU  - Si Z
AD  - National Energy R&D Center for Biorefinery, Beijing University of Chemical 
      Technology, No. 15 North 3rd Ring East Road, Beijing, 100029, P. R. China.
FAU - Li, Jingfang
AU  - Li J
AD  - State Key Laboratory of Chemical Resource Engineering & Beijing Laboratory of 
      Biomedical Materials, Beijing University of Chemical Technology, No. 15 North 3rd 
      Ring East Road, Beijing, 100029, P. R. China.
FAU - Ma, Liang
AU  - Ma L
AD  - Beijing Advanced Innovation Centre of Soft Matter and Engineering, Beijing 
      University of Chemical Technology, No. 15 North 3rd Ring East Road, Beijing, 
      100029, P. R. China.
FAU - Cai, Di
AU  - Cai D
AD  - National Energy R&D Center for Biorefinery, Beijing University of Chemical 
      Technology, No. 15 North 3rd Ring East Road, Beijing, 100029, P. R. China.
FAU - Li, Shufeng
AU  - Li S
AD  - National Energy R&D Center for Biorefinery, Beijing University of Chemical 
      Technology, No. 15 North 3rd Ring East Road, Beijing, 100029, P. R. China.
FAU - Baeyens, Jan
AU  - Baeyens J
AD  - Beijing Advanced Innovation Centre of Soft Matter and Engineering, Beijing 
      University of Chemical Technology, No. 15 North 3rd Ring East Road, Beijing, 
      100029, P. R. China.
AD  - School of Engineering, University of Warwick, Coventry, CV4 7AL, UK.
FAU - Degreve, Jan
AU  - Degreve J
AD  - Department of Chemical Engineering, Katholieke Universiteit Leuven, W. de 
      Croylaan 46, B-3001, Leuven, Belgium.
FAU - Nie, Jun
AU  - Nie J
AD  - State Key Laboratory of Chemical Resource Engineering & Beijing Laboratory of 
      Biomedical Materials, Beijing University of Chemical Technology, No. 15 North 3rd 
      Ring East Road, Beijing, 100029, P. R. China.
FAU - Tan, Tianwei
AU  - Tan T
AD  - National Energy R&D Center for Biorefinery, Beijing University of Chemical 
      Technology, No. 15 North 3rd Ring East Road, Beijing, 100029, P. R. China.
FAU - Qin, Peiyong
AU  - Qin P
AUID- ORCID: 0000-0003-1203-9060
AD  - National Energy R&D Center for Biorefinery, Beijing University of Chemical 
      Technology, No. 15 North 3rd Ring East Road, Beijing, 100029, P. R. China.
LA  - eng
GR  - 2018YFB1501703/National Key Research and Development Program of 
      China/International
GR  - 21978016/National Natural Science Foundation of China/International
GR  - 21676014/National Natural Science Foundation of China/International
GR  - 21706008/National Natural Science Foundation of China/International
GR  - 2172041/Natural Science Foundation of Beijing Municipality/International
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20191017
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - UV polymerization
OT  - membranes
OT  - n-butanol
OT  - pervaporation
OT  - polymers
EDAT- 2019/09/25 06:00
MHDA- 2019/09/25 06:01
CRDT- 2019/09/25 06:00
PHST- 2019/07/06 00:00 [received]
PHST- 2019/09/18 00:00 [revised]
PHST- 2019/09/25 06:00 [pubmed]
PHST- 2019/09/25 06:01 [medline]
PHST- 2019/09/25 06:00 [entrez]
AID - 10.1002/anie.201908386 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2019 Nov 25;58(48):17175-17179. doi: 
      10.1002/anie.201908386. Epub 2019 Oct 17.