PMID- 31552732 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20191021 LR - 20191022 IS - 1944-8252 (Electronic) IS - 1944-8244 (Linking) VI - 11 IP - 41 DP - 2019 Oct 16 TI - Anisotropic Polyaniline/SWCNT Composite Films Prepared by in Situ Electropolymerization on Highly Oriented Polyethylene for High-Efficiency Ammonia Sensor. PG - 38169-38176 LID - 10.1021/acsami.9b13336 [doi] AB - Anisotropic composite films of polyaniline (PANI) with single-walled carbon nanotube (SWCNT) were prepared by in situ electropolymerization on highly oriented high-density polyethylene (HDPE) films. Polarized UV-vis and Raman spectra confirm the anisotropic arrangement of PANI molecular chains in the composite films. The conductivities of 16.6 +/- 0.2 and 2.07 +/- 0.2 S cm(-1) have been obtained for doped PANI/0.8 wt % SWCNT measured along and perpendicular to the direction of the HDPE molecular chain, respectively. The response of PANI/0.8 wt % SWCNT films used as ammonia sensors is much higher along the chain direction of HDPE than that perpendicular to the chain direction of HDPE with an anisotropic ratio of 1.8 at 100 ppm ammonia. This is attributed to the well-ordered array of PANI/0.8 wt % SWCNT induced by the oriented HDPE films. Moreover, the high ammonia response for PANI/0.8 wt % SWCNT may be attributed to the charge-transfer effect between PANI and SWCNT. FAU - Jiang, Tingcong AU - Jiang T AD - State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering , Beijing University of Chemical Technology , Beijing 100029 , P. R. China. FAU - Wan, Pengbo AU - Wan P AUID- ORCID: 0000-0001-8178-4262 AD - State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering , Beijing University of Chemical Technology , Beijing 100029 , P. R. China. FAU - Ren, Zhongjie AU - Ren Z AUID- ORCID: 0000-0002-7981-4431 AD - State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering , Beijing University of Chemical Technology , Beijing 100029 , P. R. China. FAU - Yan, Shouke AU - Yan S AUID- ORCID: 0000-0003-1627-341X AD - State Key Laboratory of Chemical Resource Engineering, College of Materials Science and Engineering , Beijing University of Chemical Technology , Beijing 100029 , P. R. China. AD - Key Laboratory of Rubber-Plastics, Ministry of Education , Qingdao University of Science & Technology , Qingdao 266042 , P. R. China. LA - eng PT - Journal Article DEP - 20191007 PL - United States TA - ACS Appl Mater Interfaces JT - ACS applied materials & interfaces JID - 101504991 SB - IM OTO - NOTNLM OT - SWCNT OT - ammonia sensor OT - anisotropic OT - electrodeposition OT - polyaniline EDAT- 2019/09/26 06:00 MHDA- 2019/09/26 06:01 CRDT- 2019/09/26 06:00 PHST- 2019/09/26 06:00 [pubmed] PHST- 2019/09/26 06:01 [medline] PHST- 2019/09/26 06:00 [entrez] AID - 10.1021/acsami.9b13336 [doi] PST - ppublish SO - ACS Appl Mater Interfaces. 2019 Oct 16;11(41):38169-38176. doi: 10.1021/acsami.9b13336. Epub 2019 Oct 7.