PMID- 31559661
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200203
LR  - 20200203
IS  - 1521-3765 (Electronic)
IS  - 0947-6539 (Linking)
VI  - 26
IP  - 6
DP  - 2020 Jan 27
TI  - Dual Responsive Regulation of Host-Guest Complexation in Aqueous Media to Control 
      Partial Release of the Host.
PG  - 1292-1297
LID - 10.1002/chem.201904287 [doi]
AB  - The regulation of the concentration of a wide range of small molecules is 
      ubiquitous in biological systems because it enables them to adapt to the 
      continuous changes in the environmental conditions. Herein, we report an aqueous 
      synthetic system that provides an orchestrated, temperature and pH controlled 
      regulation of the complexation between the cyclobis(paraquat-p-phenylene) host 
      (BBox) and a 1,5-dialkyloxynaphthalene (DNP) guest attached to a well-defined 
      dual responsive copolymer composed of N-isopropylacrylamide as thermoresponsive 
      monomer and acrylic acid as pH-responsive monomer. Controlled, partial release of 
      the BBox, enabling control over its concentration, is based on the tunable 
      partial collapse of the copolymer. This colored supramolecular assembly is one of 
      the first synthetic systems providing control over the concentration of a small 
      molecule, providing great potential as both T and pH chromic materials and as a 
      basis to develop more complex systems with molecular communication.
CI  - (c) 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Guo, Hui
AU  - Guo H
AD  - School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai, 
      519082, P.R. China.
AD  - Soft Matter Sciences and Engineering, ESPCI Paris, PSL University, Sorbonne 
      University, CNRS, 75005, Paris, France.
FAU - Hourdet, Dominique
AU  - Hourdet D
AD  - Soft Matter Sciences and Engineering, ESPCI Paris, PSL University, Sorbonne 
      University, CNRS, 75005, Paris, France.
FAU - Marcellan, Alba
AU  - Marcellan A
AD  - Soft Matter Sciences and Engineering, ESPCI Paris, PSL University, Sorbonne 
      University, CNRS, 75005, Paris, France.
FAU - Stoffelbach, Francois
AU  - Stoffelbach F
AD  - CNRS, Institut Parisien de Chimie Moleculaire, UMR 8232, Sorbonne Universite, 
      Equipe Chimie des Polymeres, 75252, Paris Cedex 05, France.
FAU - Lyskawa, Joel
AU  - Lyskawa J
AD  - CNRS, ENSCL, UMR 8207-UMET-Unite Materiaux Et Transformations, Ingenierie des 
      Systemes Polymeres (ISP) team, Univ. Lille, 59000, Lille, France.
FAU - de Smet, Lieselot
AU  - de Smet L
AD  - CNRS, ENSCL, UMR 8207-UMET-Unite Materiaux Et Transformations, Ingenierie des 
      Systemes Polymeres (ISP) team, Univ. Lille, 59000, Lille, France.
AD  - Supramolecular Chemistry Group, Centre of Macromolecular Chemistry (CMaC), 
      Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 
      281 S4-bis, 9000, Ghent, Belgium.
FAU - Vebr, Aurelien
AU  - Vebr A
AD  - CNRS, ENSCL, UMR 8207-UMET-Unite Materiaux Et Transformations, Ingenierie des 
      Systemes Polymeres (ISP) team, Univ. Lille, 59000, Lille, France.
FAU - Hoogenboom, Richard
AU  - Hoogenboom R
AD  - Supramolecular Chemistry Group, Centre of Macromolecular Chemistry (CMaC), 
      Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 
      281 S4-bis, 9000, Ghent, Belgium.
FAU - Woisel, Patrice
AU  - Woisel P
AUID- ORCID: 0000-0001-5860-5107
AD  - CNRS, ENSCL, UMR 8207-UMET-Unite Materiaux Et Transformations, Ingenierie des 
      Systemes Polymeres (ISP) team, Univ. Lille, 59000, Lille, France.
LA  - eng
GR  - STRAPA project, ANR-12-BS08-0005/Agence Nationale de la Recherche/
PT  - Journal Article
DEP - 20200116
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
SB  - IM
OTO - NOTNLM
OT  - host-guest systems
OT  - molecular recognition
OT  - polymers
OT  - supramolecular chemistry
EDAT- 2019/09/29 06:00
MHDA- 2019/09/29 06:01
CRDT- 2019/09/28 06:00
PHST- 2019/09/17 00:00 [received]
PHST- 2019/09/29 06:00 [pubmed]
PHST- 2019/09/29 06:01 [medline]
PHST- 2019/09/28 06:00 [entrez]
AID - 10.1002/chem.201904287 [doi]
PST - ppublish
SO  - Chemistry. 2020 Jan 27;26(6):1292-1297. doi: 10.1002/chem.201904287. Epub 2020 
      Jan 16.