PMID- 31606705
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200303
LR  - 20200303
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 384
DP  - 2020 Feb 15
TI  - Mechanism and performance of singlet oxygen dominated peroxymonosulfate 
      activation on CoOOH nanoparticles for 2,4-dichlorophenol degradation in water.
PG  - 121350
LID - S0304-3894(19)31304-4 [pii]
LID - 10.1016/j.jhazmat.2019.121350 [doi]
AB  - Peroxymonosulfate (PMS) has gained attention as oxidant for SR-AOPs. It is 
      essential to develop a stable heterogeneous catalyst with strong hydrophilicity 
      and high electron transfer capability for PMS activating. In this study, cobalt 
      oxyhydroxide (CoOOH) was synthesized and activated PMS for degradation of 
      2,4-dichlorophenol (2,4-DCP) aiming to assess the feasibility of CoOOH/PMS 
      system. 50 mg/L of 2,4-DCP could be 100% degraded within 120 min with 0.20 g/L 
      CoOOH and 6 mM PMS. CoOOH/PMS system possessed a high degradation efficiency 
      (0.0462 min(-1)), which was about 10 and 4 times higher than Co(3)O(4)/PMS and 
      CoFe(2)O(4)/PMS system, respectively. Furthermore, it was found that CoOOH/PMS 
      system displayed effective catalytic performance over broad pH range (e.g. 3-9). 
      Importantly, the quenching tests revealed that (1)O(2) was identified as dominant 
      reactive oxygen species (ROS). Co (Ⅲ) was rapidly reduced to Co (Ⅱ) owing to the 
      efficient electron transfer rate performance of CoOOH in the catalytic reaction. 
      Then, the regeneration of Co (Ⅱ) facilitated CoOH(+) owing to the surface of 
      CoOOH with sufficient hydroxyl group, which is crucial for PMS activation and 
      reactive oxygen species-ROS generation. This study proposed an alternative 
      technology based on peroxymonosulfate catalyzed by cobalt-based hydroxide for 
      waste water treatment.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Zhang, Qihui
AU  - Zhang Q
AD  - Key Lab of Groundwater Resources and Environment, Ministry of Education, Jilin 
      University, Changchun, 130026, PR China; Jilin Provincial Key Laboratory of Water 
      Resources and Environment, Jilin University, Changchun, 130026, PR China.
FAU - He, Dan
AU  - He D
AD  - Key Lab of Groundwater Resources and Environment, Ministry of Education, Jilin 
      University, Changchun, 130026, PR China; Jilin Provincial Key Laboratory of Water 
      Resources and Environment, Jilin University, Changchun, 130026, PR China.
FAU - Li, Xinran
AU  - Li X
AD  - Key Lab of Groundwater Resources and Environment, Ministry of Education, Jilin 
      University, Changchun, 130026, PR China; Jilin Provincial Key Laboratory of Water 
      Resources and Environment, Jilin University, Changchun, 130026, PR China.
FAU - Feng, Wei
AU  - Feng W
AD  - Key Lab of Groundwater Resources and Environment, Ministry of Education, Jilin 
      University, Changchun, 130026, PR China; Jilin Provincial Key Laboratory of Water 
      Resources and Environment, Jilin University, Changchun, 130026, PR China.
FAU - Lyu, Cong
AU  - Lyu C
AD  - Key Lab of Groundwater Resources and Environment, Ministry of Education, Jilin 
      University, Changchun, 130026, PR China; Jilin Provincial Key Laboratory of Water 
      Resources and Environment, Jilin University, Changchun, 130026, PR China. 
      Electronic address: lvcong@jlu.edu.cn.
FAU - Zhang, Yifeng
AU  - Zhang Y
AD  - Department of Environmental Engineering, Technical University of Denmark, 
      DK-2800, Kongens Lyngby, Denmark.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20191005
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - CoOOH
OT  - Electron transfer
OT  - Singlet oxygen
OT  - Sulfate radical
OT  - Surface hydroxyl density
EDAT- 2019/10/14 06:00
MHDA- 2019/10/14 06:01
CRDT- 2019/10/14 06:00
PHST- 2019/06/27 00:00 [received]
PHST- 2019/09/11 00:00 [revised]
PHST- 2019/09/28 00:00 [accepted]
PHST- 2019/10/14 06:00 [pubmed]
PHST- 2019/10/14 06:01 [medline]
PHST- 2019/10/14 06:00 [entrez]
AID - S0304-3894(19)31304-4 [pii]
AID - 10.1016/j.jhazmat.2019.121350 [doi]
PST - ppublish
SO  - J Hazard Mater. 2020 Feb 15;384:121350. doi: 10.1016/j.jhazmat.2019.121350. Epub 
      2019 Oct 5.