PMID- 31652961
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200928
IS  - 2073-4360 (Electronic)
IS  - 2073-4360 (Linking)
VI  - 11
IP  - 11
DP  - 2019 Oct 24
TI  - Microwave-Assisted Classic Ullmann C-C Coupling Polymerization for 
      Acceptor-Acceptor Homopolymers.
LID - 10.3390/polym11111741 [doi]
LID - 1741
AB  - Developing cheap, clean and atomic-efficient synthetic methodologies for 
      conjugated polymers are always critical for the field of organic electronics. 
      Herein, classic Ullmann coupling polymerization is developed to synthesize a 
      series of Acceptor-Acceptor (A-A) type homopolymers with microwave-assistance, 
      which are supported by nuclear magnetic resonance (NMR), matrix-assisted laser 
      desorption/ionization time of flight mass spectrometry (MALDI-TOF), elemental 
      analysis (EA) and gel permeation chromatography (GPC). The physicochemical 
      properties of these polymers are studied by UV-vis spectroscopy, cyclic 
      voltammetry (CV), thermal gravimetric analysis (TGA), and density functional 
      theory (DFT) calculation. Furthermore, these A-A homopolymers are used as 
      acceptors for all-polymer solar cells (All-PSCs), affording a promising 
      efficiency of 3.08%, which is the highest value for A-A-homopolymer-based organic 
      solar cells.
FAU - Li, Zijie
AU  - Li Z
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. lizijie_win@163.com.
FAU - Chen, Yusheng
AU  - Chen Y
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. chenyusheng767@gmail.com.
FAU - Ye, Pan
AU  - Ye P
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. yepan1108@163.com.
FAU - Jia, Xiangli
AU  - Jia X
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. 
      jiaxiangli14@mails.ucas.edu.cn.
FAU - Wu, Xiaoxi
AU  - Wu X
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. estherwuxiaoxi@gmail.com.
FAU - Wu, Jianfei
AU  - Wu J
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. wujianfeidbj@gmail.com.
FAU - Shi, Qinqin
AU  - Shi Q
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. shiqinqin@ucas.edu.cn.
FAU - Peng, Aidong
AU  - Peng A
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. paidong@ucas.ac.cn.
FAU - Huang, Hui
AU  - Huang H
AD  - College of Materials Science and Opto-Electronic Technology & Center of Materials 
      Science and Optoelectronics Engineering & CAS Center for Excellence in 
      Topological Quantum Computation & CAS Key Laboratory of Vacuum Physic, University 
      of Chinese Academy of Sciences, Beijing 100049, China. huihuang@ucas.ac.cn.
LA  - eng
GR  - 21774130/National Natural Science Foundation of China/
GR  - 2018FYA 0305800/National Key R&D Program of China/
GR  - XDB28000000/the Strategic Priority Research Program of Chinese Academy of 
      Sciences/
GR  - 211211KYSB20170014/External Cooperation Programs of Chinese Academy of Sciences/
GR  - QYZDB-SSW-JSC046/the Key Research Program of Frontier Sciences, CAS/
GR  - XDPB08-2/Key Research Program of the Chinese Academy of Sciences/
PT  - Journal Article
DEP - 20191024
PL  - Switzerland
TA  - Polymers (Basel)
JT  - Polymers
JID - 101545357
PMC - PMC6918342
OTO - NOTNLM
OT  - A-A homopolymers
OT  - classic Ullmann coupling polymerization
OT  - microwave-assistance
OT  - organic solar cells
COIS- The authors declare no conflict of interest.
EDAT- 2019/10/28 06:00
MHDA- 2019/10/28 06:01
PMCR- 2019/10/24
CRDT- 2019/10/27 06:00
PHST- 2019/09/16 00:00 [received]
PHST- 2019/10/17 00:00 [revised]
PHST- 2019/10/19 00:00 [accepted]
PHST- 2019/10/27 06:00 [entrez]
PHST- 2019/10/28 06:00 [pubmed]
PHST- 2019/10/28 06:01 [medline]
PHST- 2019/10/24 00:00 [pmc-release]
AID - polym11111741 [pii]
AID - polymers-11-01741 [pii]
AID - 10.3390/polym11111741 [doi]
PST - epublish
SO  - Polymers (Basel). 2019 Oct 24;11(11):1741. doi: 10.3390/polym11111741.