PMID- 31707322 OWN - NLM STAT- MEDLINE DCOM- 20200214 LR - 20200214 IS - 1090-2414 (Electronic) IS - 0147-6513 (Linking) VI - 188 DP - 2020 Jan 30 TI - Dissipation of sixteen pesticide residues from various applications of commercial formulations on strawberry and their risk assessment under greenhouse conditions. PG - 109842 LID - S0147-6513(19)31173-X [pii] LID - 10.1016/j.ecoenv.2019.109842 [doi] AB - Twelve commercial pesticide formulations containing sixteen active ingredients were applied on greenhouse strawberries at recommended and double doses. The dynamics and dietary risk analysis were investigated. A modified QuEChERS method based on the use of multi-walled carbon nanotubes (MWCNTs) as adsorbent followed by LC-MS/MS and GC-MS/MS detection was utilized for sample analysis. The half-lives of studied pesticides were 4.6-12.6 days and 3.8-15.8 days from two application doses. Dietary levels from the residue concentrations of the individual pesticides at harvest was contrasted with the acceptable daily intake (ADI) and acute reference dose (ARfD). The dietary risk assessment adopt the risk quotient (RQ) for chronic risk and risk probability (RP) for long-term dietary intake risk, respectively. The dietary risk induced by the studied pesticide residues in strawberry was acceptable for consumers except the pesticide fumigants. The pesticide residues at different pre-harvest intervals (PHIs) under greenhouse conditions were compared with the established maximum residue limits (MRLs). To reduce the residue levels and potential safety risk, a longer PHI or reduced application rates should be conducted. CI - Copyright (c) 2019 Elsevier Inc. All rights reserved. FAU - Song, Le AU - Song L AD - Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, China. FAU - Zhong, Zezhi AU - Zhong Z AD - Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, China. FAU - Han, Yongtao AU - Han Y AD - Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China. FAU - Zheng, Qinglin AU - Zheng Q AD - Beijing Engineering Research Center of Food Safety Testing Instrumentatio, Beijing, 101200, China. FAU - Qin, Yuhong AU - Qin Y AD - Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, China. FAU - Wu, Qian AU - Wu Q AD - Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, China. FAU - He, Xiaoping AU - He X AD - Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, China. FAU - Pan, Canping AU - Pan C AD - Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, 100193, China. Electronic address: canpingp@cau.edu.cn. LA - eng PT - Journal Article DEP - 20191108 PL - Netherlands TA - Ecotoxicol Environ Saf JT - Ecotoxicology and environmental safety JID - 7805381 RN - 0 (Nanotubes, Carbon) RN - 0 (Pesticide Residues) SB - IM MH - Chromatography, Liquid MH - Food Contamination/*analysis MH - Fragaria/*chemistry/growth & development MH - Fruit/*chemistry/growth & development MH - Nanotubes, Carbon/chemistry MH - No-Observed-Adverse-Effect Level MH - Pesticide Residues/*analysis/toxicity MH - Risk Assessment MH - Tandem Mass Spectrometry OTO - NOTNLM OT - Health risk assessment OT - Maximum residue limits OT - Pre-harvest intervals OT - Residue dynamics OT - Risk probability OT - Risk quotient EDAT- 2019/11/11 06:00 MHDA- 2020/02/15 06:00 CRDT- 2019/11/11 06:00 PHST- 2019/06/27 00:00 [received] PHST- 2019/10/16 00:00 [revised] PHST- 2019/10/19 00:00 [accepted] PHST- 2019/11/11 06:00 [pubmed] PHST- 2020/02/15 06:00 [medline] PHST- 2019/11/11 06:00 [entrez] AID - S0147-6513(19)31173-X [pii] AID - 10.1016/j.ecoenv.2019.109842 [doi] PST - ppublish SO - Ecotoxicol Environ Saf. 2020 Jan 30;188:109842. doi: 10.1016/j.ecoenv.2019.109842. Epub 2019 Nov 8.