PMID- 31739253 OWN - NLM STAT- MEDLINE DCOM- 20200403 LR - 20200403 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 243 DP - 2020 Mar TI - Migration and distribution characteristics of organic and inorganic fractions in condensable particulate matter emitted from an ultralow emission coal-fired power plant. PG - 125346 LID - S0045-6535(19)32586-X [pii] LID - 10.1016/j.chemosphere.2019.125346 [doi] AB - Condensable particulate matter (CPM) is the main part of total particulate matter (TPM) discharged from coal-fired power plants. In this study, a new analytical method was proposed for accurately quantifying the organic components including n-alkanes and phthalates in CPM that sampled from an ultralow emission coal-fired plant by using the Gas Chromatography-Mass Spectrometer (GC-MS) and the mixed standard solution. The organic fraction made up 53.13%, 50.90%, 52.44% of the CPM tested at the outlet of the low-low temperature electrostatic precipitator (LLT-ESP), the wet flue gas desulfurization (WFGD) and the wet electrostatic precipitator (WESP), respectively. The total concentration of 19 kinds of n-alkanes range from 0.328 mg/Nm(3) to 0.854mg/Nm(3) with C(24)-C(30) becoming the major n-alkanes compounds in all sampling sites. The chief component of the tested phthalate was the di-n-butyl ortho-phthalate (DBP) which comprised 95.43%, 88.29%, 95.33% of the total of five kinds of phthalates. The WFGD contributed to the reduction of phthalates and the generation of n-alkanes while the effects on WESP were opposite. Furthermore, the existing air pollution control devices (APCDs) had no significant selection for the removal of n-alkanes causing the proportions of different n-alkanes were almost the same in different sampling sites. Also, the mechanism of the APCDs on the removal of CPM organic fraction was proposed primarily. The proportion of organic components measured in the organic fractions was less than 15%. Accurate quantification of other organic compounds and the mechanism of pollutant removal should be studied in the future. CI - Copyright (c) 2019 Elsevier Ltd. All rights reserved. FAU - Song, Jianwu AU - Song J AD - State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China. FAU - Lu, Shengyong AU - Lu S AD - State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China. Electronic address: lushy@zju.edu.cn. FAU - Wu, Yujia AU - Wu Y AD - State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China. FAU - Zhou, Chenyang AU - Zhou C AD - State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China. FAU - Li, Xiaodong AU - Li X AD - State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China. FAU - Li, Jingwei AU - Li J AD - State Key Laboratory of Clean Energy Utilization, Institute for Thermal Power Engineering, Zhejiang University, Hangzhou, 310027, China; School of Energy and Power Engineering, Shandong University, Shandong, 250061, China. LA - eng PT - Journal Article DEP - 20191111 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Air Pollutants) RN - 0 (Coal) RN - 0 (Gases) RN - 0 (Particulate Matter) SB - IM MH - Air Pollutants/*analysis MH - Coal/analysis MH - *Environmental Monitoring MH - Gases MH - Particulate Matter/*analysis MH - *Power Plants MH - Static Electricity OTO - NOTNLM OT - Coal-fired power plant OT - Migration and distribution characteristics OT - Organic pollutant in the condensable particulate matter OT - Removal process in air pollution control devices EDAT- 2019/11/19 06:00 MHDA- 2020/04/04 06:00 CRDT- 2019/11/19 06:00 PHST- 2019/09/03 00:00 [received] PHST- 2019/11/08 00:00 [revised] PHST- 2019/11/08 00:00 [accepted] PHST- 2019/11/19 06:00 [pubmed] PHST- 2020/04/04 06:00 [medline] PHST- 2019/11/19 06:00 [entrez] AID - S0045-6535(19)32586-X [pii] AID - 10.1016/j.chemosphere.2019.125346 [doi] PST - ppublish SO - Chemosphere. 2020 Mar;243:125346. doi: 10.1016/j.chemosphere.2019.125346. Epub 2019 Nov 11.