PMID- 31754860
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200129
LR  - 20200129
IS  - 1436-5073 (Electronic)
IS  - 0026-3672 (Linking)
VI  - 186
IP  - 12
DP  - 2019 Nov 21
TI  - Magnetic partially carbonized cellulose nanocrystal-based magnetic solid phase 
      extraction for the analysis of triazine and triazole pesticides in water.
PG  - 825
LID - 10.1007/s00604-019-3911-x [doi]
AB  - Magnetic partially carbonized cellulose nanocrystals (MPC-CNC) were obtained by 
      sulfuric acid treatment of microcrystalline cellulose (MCC) and then loaded with 
      magnetic Fe(3)O(4) nanoparticles. The material is shown to be a viable material 
      for magnetic solid phase extraction of triazine and triazole pesticides from 
      water. The pesticides (specifically: simazine, ametryn, prometryn, terbutryn, 
      atrazine, triadimenol, epoxiconazole, myclobutanil, triadimefon and tebuconazole) 
      were quantified by ultra HPLC in tandem with a triple quadrupole mass 
      spectrometry (UHPLC-MS/MS). The effects of NaCl concentration, amount of 
      adsorbent, vortex time, sample volume and pH value on extraction efficiency were 
      optimized by Plackett-Burman design and Box-Behnken design methods. Under the 
      optimal conditions, the method shows the following figures of merit: (a) Linear 
      responses in the range from 0.02-10 mug L(-1); (b) detection limits between 2.2 to 
      6.1 ng L(-1) (for S/N = 3); (c) recoveries from spiked samples of 73.7-117.1% 
      with relative standard deviations (RSDs) of 2.0-15.7%; and (d) an enrichment 
      factor of 75. The method was successfully applied to the determination of the 
      pesticides in five environmental water samples. Graphical abstract Schematic 
      representation of the process of magnetic solid phase extracting pesticides in 
      water using MPC-CNC. MCC-microcrystalline cellulose; PC-CNC- partially carbonized 
      cellulose nanocrystals; MPC-CNC-magnetic partially carbonized cellulose 
      nanocrystals.
FAU - Yi, Xiaotong
AU  - Yi X
AD  - Beijing Advanced Innovation Center for Food Nutrition and Human Health, 
      Department of Applied Chemistry, China Agricultural University, Beijing, 100193, 
      People's Republic of China.
FAU - Liu, Chang
AU  - Liu C
AD  - Beijing Advanced Innovation Center for Food Nutrition and Human Health, 
      Department of Applied Chemistry, China Agricultural University, Beijing, 100193, 
      People's Republic of China.
FAU - Liu, Xueke
AU  - Liu X
AD  - Beijing Advanced Innovation Center for Food Nutrition and Human Health, 
      Department of Applied Chemistry, China Agricultural University, Beijing, 100193, 
      People's Republic of China.
FAU - Wang, Peng
AU  - Wang P
AD  - Beijing Advanced Innovation Center for Food Nutrition and Human Health, 
      Department of Applied Chemistry, China Agricultural University, Beijing, 100193, 
      People's Republic of China.
FAU - Zhou, Zhiqiang
AU  - Zhou Z
AD  - Beijing Advanced Innovation Center for Food Nutrition and Human Health, 
      Department of Applied Chemistry, China Agricultural University, Beijing, 100193, 
      People's Republic of China.
FAU - Liu, Donghui
AU  - Liu D
AD  - Beijing Advanced Innovation Center for Food Nutrition and Human Health, 
      Department of Applied Chemistry, China Agricultural University, Beijing, 100193, 
      People's Republic of China.
LA  - eng
GR  - 21307155/National Natural Science Foundation of China/International
GR  - 21677175/National Natural Science Foundation of China/International
GR  - 2017LX001/Chinese Universities Scientific Fund/International
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20191121
PL  - Austria
TA  - Mikrochim Acta
JT  - Mikrochimica acta
JID - 7808782
SB  - IM
OTO - NOTNLM
OT  - Carbonification
OT  - Cellulose nanocrystals
OT  - Environmental water
OT  - Magnetic solid phase extraction
OT  - Triazine herbicides
OT  - Triazole fungicides
EDAT- 2019/11/23 06:00
MHDA- 2019/11/23 06:01
CRDT- 2019/11/23 06:00
PHST- 2019/05/09 00:00 [received]
PHST- 2019/10/11 00:00 [accepted]
PHST- 2019/11/23 06:00 [entrez]
PHST- 2019/11/23 06:00 [pubmed]
PHST- 2019/11/23 06:01 [medline]
AID - 10.1007/s00604-019-3911-x [pii]
AID - 10.1007/s00604-019-3911-x [doi]
PST - epublish
SO  - Mikrochim Acta. 2019 Nov 21;186(12):825. doi: 10.1007/s00604-019-3911-x.