PMID- 31771097
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200928
IS  - 2073-4360 (Electronic)
IS  - 2073-4360 (Linking)
VI  - 11
IP  - 12
DP  - 2019 Nov 22
TI  - Improvement of Rice Husk/HDPE Bio-Composites Interfacial properties by Silane 
      Coupling Agent and Compatibilizer Complementary Modification.
LID - 10.3390/polym11121928 [doi]
LID - 1928
AB  - Composites using agricultural and forestry residues as raw materials with 
      potentially high-performance, multifunctional and biodegradable ecological 
      advantages, are viewed as very promising for new-generation lightweight and 
      low-cost bio-based sustainable building materials. At present, the research on 
      wood-plastic composite materials is relatively mature. However, it is still a 
      challenge to effectively use other biomass and improve the interface of the 
      high-polymer compound system. Herein, we proposed a simple and effective method 
      to enhance the interfacial adhesion properties of rice husk fibre and High 
      Density Polyethylene (HDPE) composites by the silane coupling agent KH-550 and 
      compatibilizer Maleic anhydride grafted polyethylene (MAPE) with complementary 
      modification. It was found that the coupling agent KH-550 cross-linked with the 
      hydroxyl group on the husk fibre surface and solidified with the high polymer by 
      -NH-, -C=O- functional group generation. Compatibilizer MAPE strengthened the two 
      phases by covalently bonding with an ester linkage and lowered the roughness of 
      the cross-section of the composites. Meanwhile the modification enhanced the 
      dispersibility, and mechanical properties of the husk-high polymer compound 
      system, the bending and flexural strength were improved by 11.5% and 28.9% with 
      KH-550, and MAPE added, respectively. The flexural strength of the composites 
      increased by 40.7% after complementary modification. Furthermore, the 
      complementary modification treatment reduced the hydrophilic hydroxyl groups and 
      increased the molecular chain to improve the water-resistance, elastic modulus 
      and toughness of the composite. This study prepared a bio-composite, which is 
      expected to expand the use of agricultural and forestry residues as an extension 
      of wood-plastic composites.
FAU - Sun, Jingmeng
AU  - Sun J
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
FAU - Pang, Yao
AU  - Pang Y
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
FAU - Yang, Yingni
AU  - Yang Y
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
FAU - Zhao, Junqi
AU  - Zhao J
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
FAU - Xia, Rongqi
AU  - Xia R
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
FAU - Li, Yanchen
AU  - Li Y
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
FAU - Liu, Yi
AU  - Liu Y
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
AD  - Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry 
      University, Beijing 100083, China.
AD  - MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, 
      Beijing Forestry University, Beijing 100083, China.
FAU - Guo, Hongwu
AU  - Guo H
AD  - MOE Key Laboratory of Wooden Material Science and Application, Beijing Forestry 
      University, Beijing 100083, China.
AD  - Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry 
      University, Beijing 100083, China.
AD  - MOE Engineering Research Center of Forestry Biomass Materials and Bioenergy, 
      Beijing Forestry University, Beijing 100083, China.
LA  - eng
GR  - 2018ZY12/Fundamental Research Funds for the Central Universities/
PT  - Journal Article
DEP - 20191122
PL  - Switzerland
TA  - Polymers (Basel)
JT  - Polymers
JID - 101545357
PMC - PMC6960626
OTO - NOTNLM
OT  - bio-composite
OT  - high-density polyethylene
OT  - interface modification
OT  - rice husk
COIS- The authors declare no conflicts of interest.
EDAT- 2019/11/28 06:00
MHDA- 2019/11/28 06:01
PMCR- 2019/11/22
CRDT- 2019/11/28 06:00
PHST- 2019/11/02 00:00 [received]
PHST- 2019/11/18 00:00 [revised]
PHST- 2019/11/18 00:00 [accepted]
PHST- 2019/11/28 06:00 [entrez]
PHST- 2019/11/28 06:00 [pubmed]
PHST- 2019/11/28 06:01 [medline]
PHST- 2019/11/22 00:00 [pmc-release]
AID - polym11121928 [pii]
AID - polymers-11-01928 [pii]
AID - 10.3390/polym11121928 [doi]
PST - epublish
SO  - Polymers (Basel). 2019 Nov 22;11(12):1928. doi: 10.3390/polym11121928.