PMID- 31788732 OWN - NLM STAT- MEDLINE DCOM- 20200303 LR - 20200303 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 27 IP - 1 DP - 2020 Jan TI - Use of cork granules as an effective sustainable material to clean-up spills of crude oil and derivatives. PG - 366-378 LID - 10.1007/s11356-019-06743-1 [doi] AB - The use of cork granules for cleaning up crude oil or oil derivative spills and further oil recovery appears as a promising option due to their unique properties, which allow a high oil sorption capacity, low water pickup and excellent reuse. The present work reports the effect of oil viscosity on cork sorption capacity by using five types of oils (lubricating oil, 5.7 g(oil) g(cork)(-1); heavy oil, 4.2 g(oil) g(cork)(-1); light oil, 3.0 g(oil) g(cork)(-1); biodiesel, 2.6 g(oil) g(cork)(-1); and diesel, 2.0 g(oil) g(cork)(-1)). The cork sorption capacity for light petroleum was also evaluated as a function of temperature and sorbent particle size. Additionally, improvements on oil recovery from cork sorbents by a mechanical compression process have been achieved as a result of a design of experiments (DOE) using the response surface methodology. Such statistical technique provided remarkable results in terms of cork sorbent reusability, as the oil sorption capacity was preserved after 30 cycles of sorption-squeezing steps. The sorbed oils could be removed from the sorbent surface, collected simply by squeezing the cork granules and further reused. The best operational region yielded near 80% oil recovery, using a cork mass of 8.85 g (particle size of 2.0-4.0 mm) loaded with 43.5 mL of lubricating oil, at 5.4 bar, utilising two compressions with a duration of 2 min each. Graphical abstract. FAU - Todescato, Diego AU - Todescato D AD - Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465, Porto, Portugal. AD - Laboratory of Mass Transfer, Federal University of Santa Catarina, PO Box 476, Florianopolis, SC, CEP 88040-900, Brazil. FAU - Hackbarth, Fabiola V AU - Hackbarth FV AD - Laboratory of Mass Transfer, Federal University of Santa Catarina, PO Box 476, Florianopolis, SC, CEP 88040-900, Brazil. FAU - Carvalho, Pedro J AU - Carvalho PJ AD - CICECO-Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193, Aveiro, Portugal. FAU - Ulson de Souza, Antonio A AU - Ulson de Souza AA AD - Laboratory of Mass Transfer, Federal University of Santa Catarina, PO Box 476, Florianopolis, SC, CEP 88040-900, Brazil. FAU - Ulson de Souza, Selene M A G AU - Ulson de Souza SMAG AD - Laboratory of Mass Transfer, Federal University of Santa Catarina, PO Box 476, Florianopolis, SC, CEP 88040-900, Brazil. FAU - Boaventura, Rui A R AU - Boaventura RAR AD - Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465, Porto, Portugal. FAU - Granato, Miguel A AU - Granato MA AD - Departamento de Engenharias, Universidade Federal de Santa Catarina (UFSC), Campus Blumenau, Blumenau, SC, Brazil. FAU - Vilar, Vitor J P AU - Vilar VJP AUID- ORCID: 0000-0003-0943-2144 AD - Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Chemical Engineering Department, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465, Porto, Portugal. vilar@fe.up.pt. LA - eng PT - Journal Article DEP - 20191202 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Oils) RN - 0 (Petroleum) RN - 0 (Water Pollutants, Chemical) RN - 059QF0KO0R (Water) SB - IM EIN - Environ Sci Pollut Res Int. 2019 Dec 19;:. PMID: 31858410 MH - Adsorption MH - Environmental Restoration and Remediation/*methods MH - Oils MH - Particle Size MH - *Petroleum MH - Petroleum Pollution/*analysis MH - Water MH - Water Pollutants, Chemical/*analysis MH - Water Purification/methods OTO - NOTNLM OT - Cork OT - Crude oil and oil derivatives OT - Oil recovery OT - Oil sorption OT - Oil spill EDAT- 2019/12/04 06:00 MHDA- 2020/03/04 06:00 CRDT- 2019/12/03 06:00 PHST- 2019/01/24 00:00 [received] PHST- 2019/10/10 00:00 [accepted] PHST- 2019/12/04 06:00 [pubmed] PHST- 2020/03/04 06:00 [medline] PHST- 2019/12/03 06:00 [entrez] AID - 10.1007/s11356-019-06743-1 [pii] AID - 10.1007/s11356-019-06743-1 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2020 Jan;27(1):366-378. doi: 10.1007/s11356-019-06743-1. Epub 2019 Dec 2.