PMID- 31814072
OWN - NLM
STAT- MEDLINE
DCOM- 20200303
LR  - 20200303
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 27
IP  - 1
DP  - 2020 Jan
TI  - CeCu composite oxide for chlorophenol effective removal by heterogeneous 
      catalytic wet peroxide oxidation.
PG  - 846-860
LID - 10.1007/s11356-019-07042-5 [doi]
AB  - CeCu solid solution oxide catalysts were prepared by the complex method and 
      characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), 
      Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). And its 
      activity in the catalytic wet peroxide oxidation (CWPO) of 4-chlorophenol (4-CP) 
      and 2,4-dichlorophenol (2,4-DCP) in water was investigated. The results showed 
      that the Cu(2+) ions dissolved into the CeO(2) lattice to form CeCu solid 
      solution oxide with a coarse, interconnected, porous, and cotton-like morphology. 
      The metal-oxygen bonds were weakened by the formation of solid solution in the 
      CeCu oxide catalyst. This weakening facilitated the activation and decomposition 
      of the H(2)O(2) to form highly oxidative HO. species that can lead to significant 
      chlorophenol mineralization. The formation of CeCu solid solution oxide can 
      effectively inhibit the Cu ions to be leached from the used CeCu oxide catalysts, 
      which can ensure the CeCu oxide catalysts to adapt to a wide pH range of 2.1-7.9 
      and exhibit good reusability. CWPO reaction of 4-CP and 2,4-DCP molecules on CeCu 
      oxide catalysts conforms to the first-order kinetic equation: y = 6959.3x - 17.2 
      and y = 9725x - 25.4, respectively. And the reaction activation energies are 57.8 
      and 80.8 kJ/mol, respectively. The TOC removals of 4-CP and 2,4-DCP can exceed 88 
      and 82%, and the dechlorination rates of 4-CP and 2,4-DCP are higher than 95 and 
      99.5%, respectively.
FAU - Xie, Hongmei
AU  - Xie H
AD  - Chongqing Key Laboratory of Catalysis & Environmental New Materials, College of 
      Environment and Resources, Chongqing Technology and Business University, 
      Chongqing, 400067, China.
FAU - Zeng, Jia
AU  - Zeng J
AD  - Chongqing Key Laboratory of Catalysis & Environmental New Materials, College of 
      Environment and Resources, Chongqing Technology and Business University, 
      Chongqing, 400067, China.
FAU - Zhou, Guilin
AU  - Zhou G
AD  - Chongqing Key Laboratory of Catalysis & Environmental New Materials, College of 
      Environment and Resources, Chongqing Technology and Business University, 
      Chongqing, 400067, China. dicpglzhou@ctbu.edu.cn.
AD  - Engineering Research Center for Waste Oil Recovery Technology and Equipment, 
      Ministry of Education, Chongqing, 400067, China. dicpglzhou@ctbu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20191208
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Chlorophenols)
RN  - 0 (Oxides)
RN  - 0 (Peroxides)
RN  - 3DLC36A01X (4-chlorophenol)
RN  - BBX060AN9V (Hydrogen Peroxide)
SB  - IM
MH  - Catalysis
MH  - Chlorophenols/*chemistry
MH  - Halogenation
MH  - Hydrogen Peroxide/chemistry
MH  - Microscopy, Electron, Scanning
MH  - *Models, Chemical
MH  - Oxidation-Reduction
MH  - Oxides
MH  - Peroxides/chemistry
MH  - X-Ray Diffraction
OTO - NOTNLM
OT  - 2,4-Dichlorophenol
OT  - 4-Chlorophenol
OT  - Catalytic wet peroxide oxidation (CWPO)
OT  - CeCu oxide catalyst
OT  - Solid solution
OT  - Waste water
EDAT- 2019/12/10 06:00
MHDA- 2020/03/04 06:00
CRDT- 2019/12/10 06:00
PHST- 2019/07/23 00:00 [received]
PHST- 2019/11/12 00:00 [accepted]
PHST- 2019/12/10 06:00 [pubmed]
PHST- 2020/03/04 06:00 [medline]
PHST- 2019/12/10 06:00 [entrez]
AID - 10.1007/s11356-019-07042-5 [pii]
AID - 10.1007/s11356-019-07042-5 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2020 Jan;27(1):846-860. doi: 
      10.1007/s11356-019-07042-5. Epub 2019 Dec 8.