PMID- 31818670
OWN - NLM
STAT- MEDLINE
DCOM- 20210108
LR  - 20210108
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 387
DP  - 2020 Apr 5
TI  - Functionalized nanoflower-like hydroxyl magnesium silicate for effective 
      adsorption of aflatoxin B1.
PG  - 121792
LID - S0304-3894(19)31746-7 [pii]
LID - 10.1016/j.jhazmat.2019.121792 [doi]
AB  - Aflatoxin B1 (AFB1), which is widely found in food and feed, poses a serious 
      threat to the health of human and livestock. In this work, functionalized 
      nanoflower-like hydroxyl magnesium silicate (FNHMS) was synthesized for 
      adsorption of AFB1. First, bulk magnesium silicate (MS) was converted into 
      nanoflower-like hydroxyl magnesium silicate (NHMS) by hydroxylation. 
      Cetyltrimethylammonium bromide (CTMAB) modification then enhanced the 
      hydrophobicity and the affinity to AFB1 of NHMS. The adsorption performance for 
      AFB1 followed the order of MS < NHMS < FNHMS, and the adsorption performance 
      increased with the increase of the dose of CTMAB. Isothermal adsorption analysis 
      indicated that the surface of FNHMS was heterogeneous. The adsorption capacity of 
      FNHMS-0.4 to AFB1 was estimated to be 27.34 mg g(-1) and 28.61 mg g(-1) by 
      Freundlich and Dubinin-Radushkevich isotherm adsorption model, respectively. By 
      analyzing the adsorption kinetics and adsorption thermodynamics, both physical 
      adsorption and chemisorption existed in the process of AFB1 being adsorbed on 
      FNHMS-0.4. Adsorption mechanisms analysis indicated that the adsorption followed 
      the adsorption site priority of H > O > Mg. This work demonstrates that FNHMS 
      could be a promising adsorbent for removal of AFB1.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Sun, Zhiwei
AU  - Sun Z
AD  - Key Laboratory of Special Functional Materials for Ecological Environment and 
      Information (Hebei University of Technology), Ministry of Education, Tianjin 
      300130, People's Republic of China; Key Laboratory for Liquid-Solid Structural 
      Evolution and Processing of Materials, Ministry of Education (Shandong 
      University), Jinan 250061, People's Republic of China.
FAU - Huang, Di
AU  - Huang D
AD  - Key Laboratory of Special Functional Materials for Ecological Environment and 
      Information (Hebei University of Technology), Ministry of Education, Tianjin 
      300130, People's Republic of China.
FAU - Duan, Xinhui
AU  - Duan X
AD  - Key Laboratory of Special Functional Materials for Ecological Environment and 
      Information (Hebei University of Technology), Ministry of Education, Tianjin 
      300130, People's Republic of China.
FAU - Hong, Wei
AU  - Hong W
AD  - Key Laboratory of Special Functional Materials for Ecological Environment and 
      Information (Hebei University of Technology), Ministry of Education, Tianjin 
      300130, People's Republic of China.
FAU - Liang, Jinsheng
AU  - Liang J
AD  - Key Laboratory of Special Functional Materials for Ecological Environment and 
      Information (Hebei University of Technology), Ministry of Education, Tianjin 
      300130, People's Republic of China. Electronic address: 
      liangjinsheng@hebut.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20191130
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Magnesium Silicates)
RN  - 1343-88-0 (Florisil)
RN  - 9N2N2Y55MH (Aflatoxin B1)
RN  - Z7FF1XKL7A (Cetrimonium)
SB  - IM
EIN - J Hazard Mater. 2020 Feb 7;391:122185. PMID: 32044629
MH  - Adsorption
MH  - Aflatoxin B1/chemistry/*isolation & purification
MH  - Cetrimonium/chemistry
MH  - Hydroxylation
MH  - Kinetics
MH  - Magnesium Silicates/*chemistry
MH  - Nanostructures/*chemistry
MH  - Thermodynamics
OTO - NOTNLM
OT  - Adsorption
OT  - Aflatoxin B1
OT  - Cetyltrimethylammonium bromide modification
OT  - Hydroxylation
OT  - Magnesium silicate
COIS- Declaration of Competing Interest There are no conflicts to declare.
EDAT- 2019/12/11 06:00
MHDA- 2021/01/09 06:00
CRDT- 2019/12/11 06:00
PHST- 2019/09/20 00:00 [received]
PHST- 2019/11/29 00:00 [revised]
PHST- 2019/11/29 00:00 [accepted]
PHST- 2019/12/11 06:00 [pubmed]
PHST- 2021/01/09 06:00 [medline]
PHST- 2019/12/11 06:00 [entrez]
AID - S0304-3894(19)31746-7 [pii]
AID - 10.1016/j.jhazmat.2019.121792 [doi]
PST - ppublish
SO  - J Hazard Mater. 2020 Apr 5;387:121792. doi: 10.1016/j.jhazmat.2019.121792. Epub 
      2019 Nov 30.