PMID- 31822066
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200113
LR  - 20200113
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 12
IP  - 1
DP  - 2020 Jan 8
TI  - Photo-Driven Self-Healing of Arbitrary Nondestructive Damage in 
      Polyethylene-Based Nanocomposites.
PG  - 1650-1657
LID - 10.1021/acsami.9b19440 [doi]
AB  - Polymer products with precise shape recovery behavior are highly desired for 
      practical applications owing to excellent processability and mechanical 
      properties compared with metallic or inorganic materials. Shape memory polymers 
      (SMPs) provide a solution for this end, but the design and scalable fabrication 
      of photothermal controllable SMPs with accurate, rapid, and repeatable recovery 
      behaviors are still great challenges. In this work, polyurethane/sulfonated 
      carbon nanotube (PU/S-CNT) composite particles are introduced into a cross-linked 
      high-density polyethylene (HDPE) as a functional dispersed phase to realize 
      photo-driven fast shape recovery in cheap polymer composite materials. It is 
      found that microcracks can be induced by the PU/S-CNT composite particles during 
      deformation, generating a particular microparticle in a microcrack (MC-MP) 
      structure. The MC-MP microstructure significantly improves the photothermal 
      conversion efficiency, thereby accelerating the photo-driven shape self-healing 
      of arbitrary nondestructive material damage. It is also found that proper 
      cross-linking of the matrix, HDPE, greatly improves the recovery performance of 
      the materials. This strategy based on the MC-MP microstructure and cross-linked 
      matrix is also instructive for designing new SMPs using other polymer materials.
FAU - Yu, Peng
AU  - Yu P
AD  - College of Polymer Science and Engineering, State Key Laboratory of Polymer 
      Materials Engineering , Sichuan University , Chengdu 610065 , Sichuan , People's 
      Republic of China.
FAU - Guo, Xiao-Shuai
AU  - Guo XS
AD  - College of Polymer Science and Engineering, State Key Laboratory of Polymer 
      Materials Engineering , Sichuan University , Chengdu 610065 , Sichuan , People's 
      Republic of China.
FAU - Bao, Rui-Ying
AU  - Bao RY
AUID- ORCID: 0000-0002-1373-7154
AD  - College of Polymer Science and Engineering, State Key Laboratory of Polymer 
      Materials Engineering , Sichuan University , Chengdu 610065 , Sichuan , People's 
      Republic of China.
FAU - Liu, Zheng-Ying
AU  - Liu ZY
AD  - College of Polymer Science and Engineering, State Key Laboratory of Polymer 
      Materials Engineering , Sichuan University , Chengdu 610065 , Sichuan , People's 
      Republic of China.
FAU - Yang, Ming-Bo
AU  - Yang MB
AUID- ORCID: 0000-0001-7950-7645
AD  - College of Polymer Science and Engineering, State Key Laboratory of Polymer 
      Materials Engineering , Sichuan University , Chengdu 610065 , Sichuan , People's 
      Republic of China.
FAU - Yang, Wei
AU  - Yang W
AUID- ORCID: 0000-0003-0198-1632
AD  - College of Polymer Science and Engineering, State Key Laboratory of Polymer 
      Materials Engineering , Sichuan University , Chengdu 610065 , Sichuan , People's 
      Republic of China.
LA  - eng
PT  - Journal Article
DEP - 20191220
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - cross-linking
OT  - microcracks
OT  - photo-driven self-recovery
OT  - photothermal efficiency
OT  - shape memory polymer
EDAT- 2019/12/12 06:00
MHDA- 2019/12/12 06:01
CRDT- 2019/12/12 06:00
PHST- 2019/12/12 06:00 [pubmed]
PHST- 2019/12/12 06:01 [medline]
PHST- 2019/12/12 06:00 [entrez]
AID - 10.1021/acsami.9b19440 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2020 Jan 8;12(1):1650-1657. doi: 
      10.1021/acsami.9b19440. Epub 2019 Dec 20.