PMID- 31889106 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210110 IS - 2045-2322 (Electronic) IS - 2045-2322 (Linking) VI - 9 IP - 1 DP - 2019 Dec 30 TI - Effective reinforcements for thermoplastics based on carbon nanotubes of oil fly ash. PG - 20288 LID - 10.1038/s41598-019-56777-1 [doi] LID - 20288 AB - Carbon nanotubes (CNTs) are widely investigated for preparing polymer nanocomposites, owing to their unique mechanical properties. However, dispersing CNTs uniformly in a polymer matrix and controlling their entanglement/agglomeration are still big technical challenges to be overcome. The costs of their raw materials and production are also still high. In this work, we propose the use of CNTs grown on oil fly ash to solve these issues. The CNTs of oil fly ash were evaluated as reinforcing materials for some common thermoplastics. High-density polyethylene (HDPE) was mainly reinforced with various weight fractions of CNTs. Xylene was used as a solvent to dissolve HDPE and to uniformly disperse the CNTs. Significantly enhanced mechanical properties of HDPE reinforced at a low weight fraction of these CNTs (1-2 wt.%), mainly the tensile strength, Young's modulus, stiffness, and hardness, were observed. The tensile strength and Young's modulus were enhanced by ~20 and 38%, respectively. Moreover, the nanoindentation results were found to be in support to these findings. Polycarbonate, polypropylene, and polystyrene were also preliminarily evaluated after reinforcement with 1 wt.% CNTs. The tensile strength and Young's Modulus were increased after reinforcement with CNTs. These results demonstrate that the CNTs of the solid waste, oil fly ash, might serve as an appropriate reinforcing material for different thermoplastics polymers. FAU - Salah, Numan AU - Salah N AD - Centre of Nanotechnology, King Abdulaziz University, Jeddah, Saudi Arabia. nsalah@kau.edu.sa. FAU - Alfawzan, Abdulrahman Muhammad AU - Alfawzan AM AD - SABIC Plastic Application Development Center, Riyadh, 11551, Saudi Arabia. FAU - Saeed, Abdu AU - Saeed A AD - Centre of Nanotechnology, King Abdulaziz University, Jeddah, Saudi Arabia. AD - Department of Physics, Faculty of Sciences, King Abdulaziz University, Jeddah, Saudi Arabia. FAU - Alshahrie, Ahmed AU - Alshahrie A AD - Centre of Nanotechnology, King Abdulaziz University, Jeddah, Saudi Arabia. AD - Department of Physics, Faculty of Sciences, King Abdulaziz University, Jeddah, Saudi Arabia. FAU - Allafi, Waleed AU - Allafi W AD - SABIC Plastic Application Development Center, Riyadh, 11551, Saudi Arabia. LA - eng PT - Journal Article DEP - 20191230 PL - England TA - Sci Rep JT - Scientific reports JID - 101563288 SB - IM PMC - PMC6937296 COIS- The authors declare no competing interests. EDAT- 2020/01/01 06:00 MHDA- 2020/01/01 06:01 PMCR- 2019/12/30 CRDT- 2020/01/01 06:00 PHST- 2019/09/28 00:00 [received] PHST- 2019/12/09 00:00 [accepted] PHST- 2020/01/01 06:00 [entrez] PHST- 2020/01/01 06:00 [pubmed] PHST- 2020/01/01 06:01 [medline] PHST- 2019/12/30 00:00 [pmc-release] AID - 10.1038/s41598-019-56777-1 [pii] AID - 56777 [pii] AID - 10.1038/s41598-019-56777-1 [doi] PST - epublish SO - Sci Rep. 2019 Dec 30;9(1):20288. doi: 10.1038/s41598-019-56777-1.