PMID- 32027489
OWN - NLM
STAT- MEDLINE
DCOM- 20210113
LR  - 20210113
IS  - 1520-6882 (Electronic)
IS  - 0003-2700 (Linking)
VI  - 92
IP  - 5
DP  - 2020 Mar 3
TI  - Quantification of Trace Organophosphorus Pesticides in Environmental Water via 
      Enrichment by Magnetic-Zirconia Nanocomposites and Online Extractive Electrospray 
      Ionization Mass Spectrometry.
PG  - 4137-4145
LID - 10.1021/acs.analchem.0c00304 [doi]
AB  - A total of 15 representative organophosphorus pesticides (OPPs), a class of water 
      pollutants causing serious global concerns, have been sensitively quantified by 
      internal extractive electrospray ionization mass spectrometry (iEESI-MS) after 
      enrichment with Fe(3)O(4)-ZrO(2) innovatively synthesized in our lab by a one 
      step coprecipitation method. For the premium enrichment, the amounts of 
      Fe(3)O(4)-ZrO(2), pH value, adsorption time, type and volume of desorption 
      solvent, and shaking time of desorption were systematically optimized. Under 
      optimized conditions, the proposed method provided low limits of detection (LODs) 
      of 0.14-16.39 ng L(-1) with relative standard deviations (RSDs) of less than 
      8.7%. A wide linear response range of about 4 orders of magnitude was achieved 
      with linear coefficients (R(2)) of 0.9921-0.9999 for all the analytes tested. The 
      present method also provided good recoveries (85.4-105.9%) with acceptable 
      precision (RSDs < 7.2%) in spiked environmental water samples. Furthermore, 
      multiple analytes including dimethoate, omethoate, etc. were simultaneously 
      detected in a single sample run, which was accomplished within 1 min, resulting 
      in significantly improved analytical throughput for quantitative analysis of bulk 
      amounts of samples. The experimental results demonstrated that 
      Fe(3)O(4)-ZrO(2)-iEESI-MS provided advantages, including high sensitivity, high 
      speed, and reasonable selectivity for the detection of OPPs, showing potential 
      applications in environmental water sample analysis and environmental science.
FAU - Liu, Aiying
AU  - Liu A
AD  - State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of 
      Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
FAU - Kou, Wei
AU  - Kou W
AD  - State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of 
      Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
FAU - Zhang, Hua
AU  - Zhang H
AUID- ORCID: 0000-0003-2875-7243
AD  - State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of 
      Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
FAU - Xu, Jiaquan
AU  - Xu J
AD  - Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China 
      University of Technology, Nanchang, Jiangxi 330013, P. R. China.
FAU - Zhu, Lixue
AU  - Zhu L
AD  - State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of 
      Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
FAU - Kuang, Siliang
AU  - Kuang S
AD  - State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of 
      Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
FAU - Huang, Keke
AU  - Huang K
AUID- ORCID: 0000-0002-8995-2176
AD  - State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of 
      Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
FAU - Chen, Huanwen
AU  - Chen H
AD  - Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation, East China 
      University of Technology, Nanchang, Jiangxi 330013, P. R. China.
FAU - Jia, Qiong
AU  - Jia Q
AUID- ORCID: 0000-0002-3799-0576
AD  - College of Chemistry, Jilin University, Changchun, Jilin 130012, P. R. China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20200219
PL  - United States
TA  - Anal Chem
JT  - Analytical chemistry
JID - 0370536
RN  - 0 (Organophosphorus Compounds)
RN  - 0 (Pesticides)
RN  - 0 (Water Pollutants, Chemical)
RN  - C6V6S92N3C (Zirconium)
RN  - S38N85C5G0 (zirconium oxide)
RN  - XM0M87F357 (Ferrosoferric Oxide)
SB  - IM
MH  - Ferrosoferric Oxide/chemistry
MH  - Fresh Water/analysis
MH  - Hydrogen-Ion Concentration
MH  - Limit of Detection
MH  - *Magnetics
MH  - Nanocomposites/*chemistry
MH  - Organophosphorus Compounds/analysis/isolation & purification
MH  - Pesticides/*analysis/isolation & purification
MH  - Solid Phase Extraction
MH  - Spectrometry, Mass, Electrospray Ionization/*methods
MH  - Water Pollutants, Chemical/*analysis/isolation & purification
MH  - Zirconium/*chemistry
EDAT- 2020/02/07 06:00
MHDA- 2021/01/14 06:00
CRDT- 2020/02/07 06:00
PHST- 2020/02/07 06:00 [pubmed]
PHST- 2021/01/14 06:00 [medline]
PHST- 2020/02/07 06:00 [entrez]
AID - 10.1021/acs.analchem.0c00304 [doi]
PST - ppublish
SO  - Anal Chem. 2020 Mar 3;92(5):4137-4145. doi: 10.1021/acs.analchem.0c00304. Epub 
      2020 Feb 19.