PMID- 32036114
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200323
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 567
DP  - 2020 May 1
TI  - The lithium ions storage behavior of heteroatom-mediated echinus-like porous 
      carbon spheres: From co-doping to multi-atom doping.
PG  - 54-64
LID - S0021-9797(20)30121-1 [pii]
LID - 10.1016/j.jcis.2020.01.107 [doi]
AB  - This study proposed a facile method to prepare echinus-like porous carbon spheres 
      (PCS) with different heteroatom doping for lithium ions battery (LIBs). A 
      metal-organophosphine framework (MOPF) was synthesized by employing riboflavin 
      sodium phosphate as an organic ligand to conjugate with metal ions and then 
      carbonized at mild temperature, leading to the formation of heteroatom doped PCS 
      (H-PCS). As a result, (N, P) co-, (N, P, Ni) tri-, (N, P, Co) tri- and (N, Ni, 
      Co, P) tetra-doped PCS were obtained to examine the insight into lithium-ion 
      storage behavior of H-PCS. It was found that the specific surface area, pore 
      texture and structural defects of H-PCS were dependent on doping of heteroatoms 
      as well as the charge transfer resistance and Li-ion diffusion coefficient. 
      Significantly, the redox reaction potential during the charge/discharge could be 
      mediated upon the doping. Thus, when evaluated as anode for LIBs, the (N, Ni, Co, 
      P) tetra-doped PCS exhibited highly reversible capacity of 680 mAh g(-1) at 0.1 A 
      g(-1), excellent rate capability (115.9 mAh g(-1) at 1.0 A g(-1)) and superior 
      cycling performance (399.6 mAh g(-1) at 0.1 A g(-1)). Moreover, the cyclic 
      voltammogram measurements demonstrated that the doping of metal atoms was 
      favorable for improving the capacitive contribution of surface limited diffusion. 
      Thus, this work highlighted the importance of HCP with defined doping which could 
      be considered as one of the prominent candidates for high-performance LIBs' 
      anode.
CI  - Copyright (c) 2020 Elsevier Inc. All rights reserved.
FAU - Chen, Zhuo
AU  - Chen Z
AD  - Ningxia Key Laboratory of Photovoltaic Materials, Ningxia University, Yinchuan, 
      Ningxia 750021, PR China.
FAU - Li, Haibo
AU  - Li H
AD  - Ningxia Key Laboratory of Photovoltaic Materials, Ningxia University, Yinchuan, 
      Ningxia 750021, PR China. Electronic address: lihaibo@nxu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20200131
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
SB  - IM
OTO - NOTNLM
OT  - Energy storage
OT  - Heteroatom doping
OT  - Porous carbon spheres
OT  - Sol-gel method
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2020/02/10 06:00
MHDA- 2020/02/10 06:01
CRDT- 2020/02/10 06:00
PHST- 2019/12/04 00:00 [received]
PHST- 2020/01/23 00:00 [revised]
PHST- 2020/01/28 00:00 [accepted]
PHST- 2020/02/10 06:00 [pubmed]
PHST- 2020/02/10 06:01 [medline]
PHST- 2020/02/10 06:00 [entrez]
AID - S0021-9797(20)30121-1 [pii]
AID - 10.1016/j.jcis.2020.01.107 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2020 May 1;567:54-64. doi: 10.1016/j.jcis.2020.01.107. 
      Epub 2020 Jan 31.