PMID- 32082959 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20240329 IS - 2190-4286 (Print) IS - 2190-4286 (Electronic) IS - 2190-4286 (Linking) VI - 11 DP - 2020 TI - Size effects of graphene nanoplatelets on the properties of high-density polyethylene nanocomposites: morphological, thermal, electrical, and mechanical characterization. PG - 167-179 LID - 10.3762/bjnano.11.14 [doi] AB - High-density polyethylene (HDPE)-based nanocomposites incorporating three different types of graphene nanoplatelets (GnPs) were fabricated to investigate the size effects of GnPs in terms of both lateral size and thickness on the morphological, thermal, electrical, and mechanical properties. The results show that the inclusion of GnPs enhance the thermal, electrical, and mechanical properties of HDPE-based nanocomposites regardless of GnP size. Nevertheless, the most significant enhancement of the thermal and electrical conductivities and the lowest electrical percolation threshold were achieved with GnPs of a larger lateral size. This could have been attributed to the fact that the GnPs of larger lateral size exhibited a better dispersion in HDPE and formed conductive pathways easily observable in scanning electron microscope (SEM) images. Our results show that the lateral size of GnPs was a more regulating factor for the above-mentioned nanocomposite properties compared to their thickness. For a given lateral size, thinner GnPs showed significantly higher electrical conductivity and a lower percolation threshold than thicker ones. On the other hand, in terms of thermal conductivity, a remarkable amount of enhancement was observed only above a certain filler concentration. The results demonstrate that GnPs with smaller lateral size and larger thickness lead to lower enhancement of the samples' mechanical properties due to poorer dispersion compared to the others. In addition, the size of the GnPs had no considerable effect on the melting and crystallization properties of the HDPE/GnP nanocomposites. CI - Copyright (c) 2020, Evgin et al.; licensee Beilstein-Institut. FAU - Evgin, Tuba AU - Evgin T AUID- ORCID: 0000-0002-8245-3075 AD - Dokuz Eylul University, The Graduate School of Natural and Applied Sciences, Mechanical Engineering Department, Tinaztepe Campus, 35397, Buca, Izmir, Turkey. AD - Dokuz Eylul University, Engineering Faculty, Mechanical Engineering Department, Tinaztepe Campus, 35397, Buca, Izmir, Turkey. FAU - Turgut, Alpaslan AU - Turgut A AUID- ORCID: 0000-0003-1114-589X AD - Dokuz Eylul University, Engineering Faculty, Mechanical Engineering Department, Tinaztepe Campus, 35397, Buca, Izmir, Turkey. FAU - Hamaoui, Georges AU - Hamaoui G AUID- ORCID: 0000-0001-8451-3986 AD - GRESPI, Multiscale Thermophysics Lab, Universite de Reims Champagne-Ardenne URCA, Reims, France. FAU - Spitalsky, Zdenko AU - Spitalsky Z AUID- ORCID: 0000-0003-2589-9035 AD - Polymer Institute, SAS, Dubravska cesta 9, 845 41 Bratislava, Slovak Republic. FAU - Horny, Nicolas AU - Horny N AUID- ORCID: 0000-0003-1633-7989 AD - GRESPI, Multiscale Thermophysics Lab, Universite de Reims Champagne-Ardenne URCA, Reims, France. FAU - Micusik, Matej AU - Micusik M AD - Polymer Institute, SAS, Dubravska cesta 9, 845 41 Bratislava, Slovak Republic. FAU - Chirtoc, Mihai AU - Chirtoc M AD - GRESPI, Multiscale Thermophysics Lab, Universite de Reims Champagne-Ardenne URCA, Reims, France. FAU - Sarikanat, Mehmet AU - Sarikanat M AD - Department of Mechanical Engineering, Ege University, 35100, Bornova, Izmir, Turkey. FAU - Omastova, Maria AU - Omastova M AUID- ORCID: 0000-0003-0210-5861 AD - Polymer Institute, SAS, Dubravska cesta 9, 845 41 Bratislava, Slovak Republic. LA - eng PT - Journal Article DEP - 20200114 PL - Germany TA - Beilstein J Nanotechnol JT - Beilstein journal of nanotechnology JID - 101551563 PMC - PMC7006480 OTO - NOTNLM OT - electrical properties OT - graphene nanoplatelets OT - mechanical properties OT - polymer matrix composites (PMCs) OT - thermal properties EDAT- 2020/02/23 06:00 MHDA- 2020/02/23 06:01 PMCR- 2020/01/14 CRDT- 2020/02/22 06:00 PHST- 2019/06/28 00:00 [received] PHST- 2019/12/10 00:00 [accepted] PHST- 2020/02/22 06:00 [entrez] PHST- 2020/02/23 06:00 [pubmed] PHST- 2020/02/23 06:01 [medline] PHST- 2020/01/14 00:00 [pmc-release] AID - 10.3762/bjnano.11.14 [doi] PST - epublish SO - Beilstein J Nanotechnol. 2020 Jan 14;11:167-179. doi: 10.3762/bjnano.11.14. eCollection 2020.