PMID- 32123767
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200928
IS  - 2405-8440 (Print)
IS  - 2405-8440 (Electronic)
IS  - 2405-8440 (Linking)
VI  - 6
IP  - 2
DP  - 2020 Feb
TI  - A review of thermal homogeneous catalytic deoxygenation reactions for valuable 
      products.
PG  - e03446
LID - 10.1016/j.heliyon.2020.e03446 [doi]
LID - e03446
AB  - To remove high oxygen content is important to make high quality oil and valuable 
      products. In this paper, the research on homogeneous catalytic deoxygenation 
      reactions, including decarboxylation (DCX)/decarbonylation (DCN), 
      hydrodeoxygenation (HDO) is reviewed. Based on DCX/DCN, the classic radical 
      reactions such as the Barton decarboxylation, Henkel, Hunsdiecker and Kochi 
      reactions were introduced, the practice and overall performance are also 
      discussed. In addition, the different reaction pathways and mechanisms were 
      demonstrated and the key chemical processes have been selected from the 
      literature as examples to elaborate the critical emphasis on the mechanistic 
      understanding. The applications of the catalytic deoxygenation reactions for 
      high-value products have also been highlighted. Overall, this review provides 
      insight discussions on the DO issues and progresses in homogeneous catalytic 
      aspects.
CI  - (c) 2020 Published by Elsevier Ltd.
FAU - Kong, Zhaoni
AU  - Kong Z
AD  - Faculty of Environmental Science and Engineering, Kunming University of Science 
      and Technology, Kunming 650500, China.
FAU - He, Liang
AU  - He L
AD  - Faculty of Chemical Engineering, Kunming University of Science and Technology, 
      Kunming, 650500, China.
FAU - Shi, Yuzheng
AU  - Shi Y
AD  - Faculty of Environmental Science and Engineering, Kunming University of Science 
      and Technology, Kunming 650500, China.
FAU - Guan, Qingqing
AU  - Guan Q
AD  - Faculty of Environmental Science and Engineering, Kunming University of Science 
      and Technology, Kunming 650500, China.
FAU - Ning, Ping
AU  - Ning P
AD  - Faculty of Environmental Science and Engineering, Kunming University of Science 
      and Technology, Kunming 650500, China.
LA  - eng
PT  - Journal Article
PT  - Review
DEP - 20200220
PL  - England
TA  - Heliyon
JT  - Heliyon
JID - 101672560
PMC - PMC7036526
OTO - NOTNLM
OT  - Bio-oil
OT  - Bioconversion
OT  - Catalyst
OT  - Chemical engineering
OT  - Deoxygenation (DO)
OT  - Energy sustainability
OT  - Fuel technology
OT  - Homogeneous catalysis
OT  - Natural product chemistry
OT  - Upgrading
EDAT- 2020/03/04 06:00
MHDA- 2020/03/04 06:01
PMCR- 2020/02/20
CRDT- 2020/03/04 06:00
PHST- 2019/05/09 00:00 [received]
PHST- 2019/07/08 00:00 [revised]
PHST- 2020/02/14 00:00 [accepted]
PHST- 2020/03/04 06:00 [entrez]
PHST- 2020/03/04 06:00 [pubmed]
PHST- 2020/03/04 06:01 [medline]
PHST- 2020/02/20 00:00 [pmc-release]
AID - S2405-8440(20)30291-7 [pii]
AID - e03446 [pii]
AID - 10.1016/j.heliyon.2020.e03446 [doi]
PST - epublish
SO  - Heliyon. 2020 Feb 20;6(2):e03446. doi: 10.1016/j.heliyon.2020.e03446. eCollection 
      2020 Feb.