PMID- 32167412 OWN - NLM STAT- MEDLINE DCOM- 20210924 LR - 20210924 IS - 1479-487X (Electronic) IS - 0959-3330 (Linking) VI - 42 IP - 24 DP - 2021 Oct TI - Adsorption behavior of 2,4-DCP by rice straw biochar modified with CTAB. PG - 3797-3806 LID - 10.1080/09593330.2020.1743367 [doi] AB - In this study, rice straw was used as the raw materials of biomass carbon to prepare biochar at different temperatures (400 degrees C, 500 degrees C, 600 degrees C, 700 degrees C, and 800 degrees C). In addition, cetyl trimethyl ammonium bromide (CTAB) modified biochar was used to treat 2,4-dichlorophenol (2,4-DCP) in water. The influences of adsorbent dosage, solution pH, adsorption time, and initial solubility of the 2,4-DCP solution on the adsorption properties were investigated. The physicochemical properties of biochar were investigated using SEM, FT-IR, BET surface area, and pore size analysis. The results showed that the pyrolysis temperature had a great influence on the biochar structure. CTAB provided hydrophilic and hydrophobic groups to the modified biochar, which had increased adsorption capacity comparing to unmodified biochar. The pH also had a significant effect on the adsorption performance of biochar, and the adsorption performance of biochar decreased significantly under alkaline conditions. The maximum adsorption capacities of modified biochar and unmodified biochar were 59.81 and 20.89 mg/g, respectively, indicating that the adsorption capacity of modified biochar was significantly higher than that of unmodified biochar. The adsorption process of 2,4-DCP by rice straw biochar conformed to the Second-order kinetic model and the Freundlich isotherm adsorption model. FAU - Liu, Wenting AU - Liu W AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. FAU - Ren, Dajun AU - Ren D AUID- ORCID: 0000-0003-0752-4184 AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. AD - Hubei Key Laboratory for Efficient Utilization and Agglomeration of metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan, People's Republic of China. FAU - Wu, Jian AU - Wu J AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. FAU - Wang, Zhaobo AU - Wang Z AUID- ORCID: 0000-0002-8949-1373 AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. FAU - Zhang, Shuqin AU - Zhang S AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. AD - Hubei Key Laboratory for Efficient Utilization and Agglomeration of metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan, People's Republic of China. FAU - Zhang, Xiaoqin AU - Zhang X AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. AD - Hubei Key Laboratory for Efficient Utilization and Agglomeration of metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan, People's Republic of China. FAU - Gong, Xiangyi AU - Gong X AD - College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, People's Republic of China. AD - Hubei Key Laboratory for Efficient Utilization and Agglomeration of metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan, People's Republic of China. LA - eng PT - Journal Article DEP - 20200323 PL - England TA - Environ Technol JT - Environmental technology JID - 9884939 RN - 0 (Water Pollutants, Chemical) RN - 0 (biochar) RN - 16291-96-6 (Charcoal) RN - Z7FF1XKL7A (Cetrimonium) SB - IM MH - Adsorption MH - Cetrimonium MH - Charcoal MH - *Oryza MH - Spectroscopy, Fourier Transform Infrared MH - *Water Pollutants, Chemical OTO - NOTNLM OT - 2,4-DCP OT - Biochar OT - adsorption OT - mechanisms OT - modification EDAT- 2020/03/14 06:00 MHDA- 2021/09/25 06:00 CRDT- 2020/03/14 06:00 PHST- 2020/03/14 06:00 [pubmed] PHST- 2021/09/25 06:00 [medline] PHST- 2020/03/14 06:00 [entrez] AID - 10.1080/09593330.2020.1743367 [doi] PST - ppublish SO - Environ Technol. 2021 Oct;42(24):3797-3806. doi: 10.1080/09593330.2020.1743367. Epub 2020 Mar 23.