PMID- 32200243
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200702
LR  - 20200702
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 394
DP  - 2020 Jul 15
TI  - Facile synthesis of superparamagnetic beta-CD-MnFe(2)O(4) as a peroxymonosulfate 
      activator for efficient removal of 2,4- dichlorophenol: structure, performance, 
      and mechanism.
PG  - 122528
LID - S0304-3894(20)30517-3 [pii]
LID - 10.1016/j.jhazmat.2020.122528 [doi]
AB  - In this study, superparamagnetic beta-CD-MnFe(2)O(4) with a large surface area was 
      synthesized via a facile co-precipitation method, with beta-cyclodextrin (beta-CD) 
      acting as a coating agent. The as-prepared beta-CD-MnFe(2)O(4) exhibited better 
      catalytic performance than bare MnFe(2)O(4) in terms of activating 
      peroxymonosulfate (PMS) to degrade 2,4-dichlorophenol (2,4-DCP) over a broad pH 
      range of 5-11. Electron spin resonance spectroscopy (ESR) and free radical 
      quenching experiments indicate that various active species 
      (SO(4)(-)/OH/O(2)(-)/(1)O(2)) are generated in the beta-CD-MnFe(2)O(4)/PMS system 
      and that pollutants trapped in the cyclodextrin cavity are quickly degraded. 
      Various reaction parameters of the beta-CD-MnFe(2)O(4)/PMS system and the stability 
      of beta-CD-MnFe(2)O(4) were also investigated. The results indicate that 
      beta-CD-MnFe(2)O(4) is promising for use in water purification owing to its 
      excellent magnetic separation and recovery properties and good resistance to 
      humic acid (HA).
CI  - Copyright (c) 2020 Elsevier B.V. All rights reserved.
FAU - Zhou, Xiaojun
AU  - Zhou X
AD  - Key Laboratory for Colloid & Interface Chemistry of Education Ministry, 
      Department of Chemistry, Shandong University, Jinan 250100, PR China.
FAU - Kong, Lingshuai
AU  - Kong L
AD  - Key Laboratory for Colloid & Interface Chemistry of Education Ministry, 
      Department of Chemistry, Shandong University, Jinan 250100, PR China.
FAU - Jing, Zongyu
AU  - Jing Z
AD  - Key Laboratory for Colloid & Interface Chemistry of Education Ministry, 
      Department of Chemistry, Shandong University, Jinan 250100, PR China.
FAU - Wang, Shuqing
AU  - Wang S
AD  - Key Laboratory for Colloid & Interface Chemistry of Education Ministry, 
      Department of Chemistry, Shandong University, Jinan 250100, PR China.
FAU - Lai, Yongchao
AU  - Lai Y
AD  - Shandong Academy of Occupational Health and Occupational Medicine, Shandong First 
      Medical University & Shandong Academy of Medical Sciences, Jinan 250062, PR 
      China. Electronic address: suncedar@126.com.
FAU - Xie, Meng
AU  - Xie M
AD  - Key Laboratory for Applied Technology of Sophisticated Analytical Instruments of 
      Shandong Province, Analysis and Test Centre, Qilu University of Technology 
      (Shandong Academy of Sciences), Jinan 250014, China.
FAU - Ma, Long
AU  - Ma L
AD  - The Testing Center of Shandong Bureau of China Metallurgical Geology Bureau, 
      Jinan, 250100, PR China.
FAU - Feng, Zhenyu
AU  - Feng Z
AD  - Key Laboratory for Colloid & Interface Chemistry of Education Ministry, 
      Department of Chemistry, Shandong University, Jinan 250100, PR China.
FAU - Zhan, Jinhua
AU  - Zhan J
AD  - Key Laboratory for Colloid & Interface Chemistry of Education Ministry, 
      Department of Chemistry, Shandong University, Jinan 250100, PR China. Electronic 
      address: jhzhan@sdu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20200312
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - Cyclodextrin
OT  - Humic acid
OT  - Magnetic separation
OT  - MnFe(2)O(4)
OT  - Peroxymonosulfate
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2020/03/23 06:00
MHDA- 2020/03/23 06:01
CRDT- 2020/03/23 06:00
PHST- 2019/12/18 00:00 [received]
PHST- 2020/03/08 00:00 [revised]
PHST- 2020/03/11 00:00 [accepted]
PHST- 2020/03/23 06:00 [pubmed]
PHST- 2020/03/23 06:01 [medline]
PHST- 2020/03/23 06:00 [entrez]
AID - S0304-3894(20)30517-3 [pii]
AID - 10.1016/j.jhazmat.2020.122528 [doi]
PST - ppublish
SO  - J Hazard Mater. 2020 Jul 15;394:122528. doi: 10.1016/j.jhazmat.2020.122528. Epub 
      2020 Mar 12.