PMID- 32281577 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20201013 LR - 20230808 IS - 1348-2246 (Electronic) IS - 0910-6340 (Linking) VI - 36 IP - 10 DP - 2020 Oct 10 TI - Preparation of Magnetic Porous Aromatic Framework for Rapid and Efficient Removal of Organic Pollutants from Water. PG - 1157-1161 LID - 10.2116/analsci.20P013 [doi] AB - In this study, efforts were made to prepare a porous aromatic framework (PAF) with build-in magnetic nanoparticles (Fe(3)O(4)-PAF) for use as an efficient adsorbent for the removal of organic pollutants from water. The Fe(3)O(4)-PAF showed good handleability and could be recovered easily by magnetic separation. As a proof of concept, the adsorption properties of Fe(3)O(4)-PAF were investigated to remove 2,4-dichlorophenol (2,4-DCP) and bisphenol A (BPA) from water. The Fe(3)O(4)-PAF showed a fast adsorption rate, high adsorption efficiency and high adsorption capacities. It adsorbed 2,4-DCP (0.1 mmol L(-1)) and BPA (0.1 mmol L(-1)) with pseudo-second-order rate constant (k(2)) of 2.1 and 3.54 g mg(-1) min(-1), respectively. According to the Langmuir isotherm model, the maximum adsorption capacities of 2,4-DCP and BPA onto Fe(3)O(4)-PAF were calculated to be 234.74 and 233.65 mg g(-1), respectively. The Fe(3)O(4)-PAF also featured good tolerance to harsh conditions, facilitating its application in a real water environment. It could be regenerated easily and reused multiple times without obvious loss of efficiency. In summary, this study provides a general and effective way to improve the handleability of PAFs and expands the practical application of PAF-based materials. FAU - Yu, Wenjie AU - Yu W AD - School of Chemistry and Chemical Engineering, Jiangsu University, No. 301 Xuefu Road, Zhenjiang, 212013, China. FAU - Li, Hengye AU - Li H AD - School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, No. 9 Yinbing Avenue, Yancheng, 224002, China. lhy1024006@sina.com. FAU - Zhang, Lin AU - Zhang L AD - Comprehensive Testing Center, Yancheng Customs, No. 85 Kaifang Avenue, Yancheng, 224002, China. hbwhzl@126.com. FAU - Liu, Jing AU - Liu J AD - School of Pharmacy, China Pharmaceutical University, No. 24 Tongjia Lane, Nanjing, 210009, China. FAU - Kong, Fenying AU - Kong F AD - School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, No. 9 Yinbing Avenue, Yancheng, 224002, China. FAU - Wang, Wei AU - Wang W AD - School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, No. 9 Yinbing Avenue, Yancheng, 224002, China. wangw@ycit.edu.cn. AD - School of Chemistry and Chemical Engineering, Yangzhou University, No. 88 South University Road, Yangzhou, 225002, China. wangw@ycit.edu.cn. LA - eng PT - Journal Article DEP - 20200410 PL - Switzerland TA - Anal Sci JT - Analytical sciences : the international journal of the Japan Society for Analytical Chemistry JID - 8511078 SB - IM OTO - NOTNLM OT - 2,4-dichlorophenol OT - Porous aromatic frameworks OT - adsorption OT - bisphenol A OT - magnetic nanoparticles EDAT- 2020/04/14 06:00 MHDA- 2020/04/14 06:01 CRDT- 2020/04/14 06:00 PHST- 2020/04/14 06:00 [pubmed] PHST- 2020/04/14 06:01 [medline] PHST- 2020/04/14 06:00 [entrez] AID - 10.2116/analsci.20P013 [pii] AID - 10.2116/analsci.20P013 [doi] PST - ppublish SO - Anal Sci. 2020 Oct 10;36(10):1157-1161. doi: 10.2116/analsci.20P013. Epub 2020 Apr 10.