PMID- 32283853 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20240328 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 13 IP - 7 DP - 2020 Apr 9 TI - Polydopamine-Modified Al(2)O(3)/Polyurethane Composites with Largely Improved Thermal and Mechanical Properties. LID - 10.3390/ma13071772 [doi] LID - 1772 AB - Alumina/polyurethane composites were prepared via in situ polymerization and used as thermal interface materials (TIMs). The surface of alumina particles was modified using polydopamine (PDA) and then evaluated via Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TG), and Raman spectroscopy (Raman). Scanning electron microscope (SEM) images showed that PDA-Al(2)O(3) has better dispersion in a polyurethane (PU) matrix than Al(2)O(3). Compared with pure PU, the 30 wt% PDA-Al(2)O(3)/PU had 95% more Young's modulus, 128% more tensile strength, and 76% more elongation at break than the pure PU. Dynamic mechanical analysis (DMA) results showed that the storage modulus of the 30 wt% PDA-Al(2)O(3)/PU composite improved, and the glass transition temperature (Tg) shifted to higher temperatures. The thermal conductivity of the 30 wt% PDA-Al(2)O(3)/PU composite increased by 138%. Therefore, the results showed that the prepared PDA-coated alumina can simultaneously improve both the mechanical properties and thermal conductivity of PU. FAU - Du, Ruikui AU - Du R AD - North University of China, Taiyuan 030051, China. AD - Shanxi Province Polymer Composite Engineering Technology Research Center, Taiyuan 030051, China. FAU - He, Li AU - He L AD - North University of China, Taiyuan 030051, China. AD - Shanxi Province Polymer Composite Engineering Technology Research Center, Taiyuan 030051, China. FAU - Li, Peng AU - Li P AD - North University of China, Taiyuan 030051, China. AD - Shanxi Province Polymer Composite Engineering Technology Research Center, Taiyuan 030051, China. FAU - Zhao, Guizhe AU - Zhao G AD - North University of China, Taiyuan 030051, China. AD - Shanxi Province Polymer Composite Engineering Technology Research Center, Taiyuan 030051, China. LA - eng PT - Journal Article DEP - 20200409 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC7179027 OTO - NOTNLM OT - alumina OT - in situ polymerization OT - mechanical properties OT - polyurethane OT - thermal conductivity COIS- The authors declare no conflict of interest. EDAT- 2020/04/15 06:00 MHDA- 2020/04/15 06:01 PMCR- 2020/04/09 CRDT- 2020/04/15 06:00 PHST- 2020/02/15 00:00 [received] PHST- 2020/04/03 00:00 [revised] PHST- 2020/04/06 00:00 [accepted] PHST- 2020/04/15 06:00 [entrez] PHST- 2020/04/15 06:00 [pubmed] PHST- 2020/04/15 06:01 [medline] PHST- 2020/04/09 00:00 [pmc-release] AID - ma13071772 [pii] AID - materials-13-01772 [pii] AID - 10.3390/ma13071772 [doi] PST - epublish SO - Materials (Basel). 2020 Apr 9;13(7):1772. doi: 10.3390/ma13071772.