PMID- 32290944
OWN - NLM
STAT- MEDLINE
DCOM- 20200826
LR  - 20200826
IS  - 1000-8020 (Print)
IS  - 1000-8020 (Linking)
VI  - 49
IP  - 2
DP  - 2020 Mar
TI  - [Determination of thiram, propineb and metiram in mushroom by gas 
      chromatography-mass spectrometry].
PG  - 267-271
LID - 10.19813/j.cnki.weishengyanjiu.2020.02.017 [doi]
AB  - OBJECTIVE: To establish a method for determination of thiram, propineb and 
      metiram in mushroom samples by gas chromatography-mass spectrometry(GC-MS). 
      METHODS: Insoluble heavy metal salts were converted into water-soluble sodium 
      salts by alkaline buffer with strong chelating agents. Dithiocarbamates can be 
      converted into different methyl ester compounds with ion pair methylation. The GC 
      separation was performed on a DB-5 MS capillary column(30 mx0. 25 mm, 0. 25 mum). 
      The pesticides were detected by GC-MS with selective ion monitoring(SIM) and 
      quantified by external standard of working curve method. Methodsological 
      verification was carried out based on optimized sample pretreatment and GC-MS 
      condition. RESULTS: The concentrations of dithiocarbamates exhibited a good 
      linear relationship with GC-MS within a certain range. The limits of detection of 
      thiram, propineb and metiram were 0. 01, 0. 05 and 0. 05 mg/kg, respectively. 
      Furthermore, the average recoveries were from 76. 98% to 93. 52%, and the maximum 
      relative standard deviation was 11. 54%(n=6). CONCLUSION: This method is simple, 
      sensitive, accurate and reliable. All the indices meet the requirements of 
      pesticide residue detection.
FAU - Zhang, Jing
AU  - Zhang J
AD  - Zhejiang Center for Disease Control and Prevention, Hangzhou 310051, China.
FAU - Tan, Ying
AU  - Tan Y
AD  - Zhejiang Center for Disease Control and Prevention, Hangzhou 310051, China.
FAU - Feng, Liang
AU  - Feng L
AD  - Zhejiang Center for Disease Control and Prevention, Hangzhou 310051, China.
FAU - Ni, Zhunan
AU  - Ni Z
AD  - Zhejiang Center for Disease Control and Prevention, Hangzhou 310051, China.
FAU - Wang, Junlin
AU  - Wang J
AD  - Zhejiang Center for Disease Control and Prevention, Hangzhou 310051, China.
FAU - Cai, Zengxuan
AU  - Cai Z
AD  - Zhejiang Center for Disease Control and Prevention, Hangzhou 310051, China.
LA  - chi
PT  - Journal Article
PL  - China
TA  - Wei Sheng Yan Jiu
JT  - Wei sheng yan jiu = Journal of hygiene research
JID - 9426367
RN  - 0 (Pesticide Residues)
RN  - 003VPM353K (propineb)
RN  - 0D771IS0FH (Thiram)
RN  - 9006-42-2 (polymarcine)
RN  - 99Z2744345 (Ditiocarb)
RN  - X1FSB1OZPT (Zineb)
SB  - IM
MH  - *Agaricales
MH  - Ditiocarb
MH  - Gas Chromatography-Mass Spectrometry
MH  - Pesticide Residues/*analysis
MH  - Thiram
MH  - Zineb/analogs & derivatives
OTO - NOTNLM
OT  - gas chromatography-mass spectrometry
OT  - metiram
OT  - mushroom
OT  - propineb
OT  - thiram
EDAT- 2020/04/16 06:00
MHDA- 2020/08/28 06:00
CRDT- 2020/04/16 06:00
PHST- 2020/04/16 06:00 [entrez]
PHST- 2020/04/16 06:00 [pubmed]
PHST- 2020/08/28 06:00 [medline]
AID - 10.19813/j.cnki.weishengyanjiu.2020.02.017 [doi]
PST - ppublish
SO  - Wei Sheng Yan Jiu. 2020 Mar;49(2):267-271. doi: 
      10.19813/j.cnki.weishengyanjiu.2020.02.017.