PMID- 32297518 OWN - NLM STAT- MEDLINE DCOM- 20210709 LR - 20210709 IS - 1943-3530 (Electronic) IS - 0003-7028 (Linking) VI - 74 IP - 9 DP - 2020 Sep TI - Application of a Hybrid Fusion Classification Process for Identification of Microplastics Based on Fourier Transform Infrared Spectroscopy. PG - 1167-1183 LID - 10.1177/0003702820923993 [doi] AB - Microplastic research is an emerging field. Consistent accurate identification of microplastic polymer composition is vital for understanding the effect of microplastic pollution in the environment. Fourier transform infrared (FT-IR) spectroscopy is becoming commonplace for identifying microplastics. Conventional spectral identification is based on library searching, a process that utilizes a search algorithm against digital databases containing single spectra of pristine reference plastics. Several conditions on environmental microplastic particles such as weathering, additives, and residues cause spectral alterations relative to pristine reference library spectra. Thus, library searching is vulnerable to misidentification of microplastic samples. While a classification process (classifier) based on a collection of spectra can alleviate misidentification problems, optimization of each classifier (tuning parameter) is required. Additionally, erratic results relative to the particular optimized tuning parameter can occur when microplastic samples originate from new environmental or biological conditions than those defining the class. Presented in this study is a process that utilizes spectroscopic measurements in a hybrid fusion algorithm that depending on the user preference, simultaneously combines high-level fusion with low- and mid-level fusion based on an ensemble of non-optimized classifiers to assign microplastic samples into specific plastic categories (classes). The approach is demonstrated with 17 classifiers using FT-IR for binary classification of polyethylene terephthalate (PET) and high-density polyethylene (HDPE) microplastic samples from environmental sources. Other microplastic types are evaluated for non-class PET and HDPE membership. Results show that high accuracy, sensitivity, and specificity are obtained thereby reducing the risk of misidentifying microplastics. FAU - Chabuka, Beauty K AU - Chabuka BK AD - Department of Chemistry, 6640Idaho State University, Pocatello, USA. FAU - Kalivas, John H AU - Kalivas JH AUID- ORCID: 0000-0001-7056-976X AD - Department of Chemistry, 6640Idaho State University, Pocatello, USA. LA - eng PT - Journal Article DEP - 20200601 PL - United States TA - Appl Spectrosc JT - Applied spectroscopy JID - 0372406 RN - 0 (Environmental Pollutants) RN - 0 (Microplastics) RN - 0 (Polyethylene Terephthalates) RN - 9002-88-4 (Polyethylene) SB - IM MH - Environmental Monitoring/*methods MH - *Environmental Pollutants/analysis/classification MH - *Microplastics/analysis/classification MH - *Polyethylene/analysis/classification MH - *Polyethylene Terephthalates/analysis/classification MH - Spectroscopy, Fourier Transform Infrared OTO - NOTNLM OT - FT-IR OT - Fourier transform infrared spectroscopy OT - Microplastic OT - classification OT - classification maintenance OT - data fusion OT - transfer learning EDAT- 2020/04/17 06:00 MHDA- 2021/07/10 06:00 CRDT- 2020/04/17 06:00 PHST- 2020/04/17 06:00 [pubmed] PHST- 2021/07/10 06:00 [medline] PHST- 2020/04/17 06:00 [entrez] AID - 10.1177/0003702820923993 [doi] PST - ppublish SO - Appl Spectrosc. 2020 Sep;74(9):1167-1183. doi: 10.1177/0003702820923993. Epub 2020 Jun 1.