PMID- 32326106 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200928 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 10 IP - 4 DP - 2020 Apr 20 TI - Study of Silicon Nitride Inner Spacer Formation in Process of Gate-all-around Nano-Transistors. LID - 10.3390/nano10040793 [doi] LID - 793 AB - Stacked SiGe/Si structures are widely used as the units for gate-all-around nanowire transistors (GAA NWTs) which are a promising candidate beyond fin field effective transistors (FinFETs) technologies in near future. These structures deal with a several challenges brought by the shrinking of device dimensions. The preparation of inner spacers is one of the most critical processes for GAA nano-scale transistors. This study focuses on two key processes: inner spacer film conformal deposition and accurate etching. The results show that low pressure chemical vapor deposition (LPCVD) silicon nitride has a good film filling effect; a precise and controllable silicon nitride inner spacer structure is prepared by using an inductively coupled plasma (ICP) tool and a new gas mixtures of CH(2)F(2)/CH(4)/O(2)/Ar. Silicon nitride inner spacer etch has a high etch selectivity ratio, exceeding 100:1 to Si and more than 30:1 to SiO(2). High anisotropy with an excellent vertical/lateral etch ratio exceeding 80:1 is successfully demonstrated. It also provides a solution to the key process challenges of nano-transistors beyond 5 nm node. FAU - Li, Junjie AU - Li J AUID- ORCID: 0000-0001-5191-7992 AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Li, Yongliang AU - Li Y AUID- ORCID: 0000-0002-5590-861X AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Zhou, Na AU - Zhou N AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Xiong, Wenjuan AU - Xiong W AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Wang, Guilei AU - Wang G AUID- ORCID: 0000-0002-1311-8863 AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Zhang, Qingzhu AU - Zhang Q AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - State Key Laboratory of Advanced Materials for Smart Sensing, General Research Institute for Nonferrous Metals, Beijing 100088, China. FAU - Du, Anyan AU - Du A AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Gao, Jianfeng AU - Gao J AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Kong, Zhenzhen AU - Kong Z AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Lin, Hongxiao AU - Lin H AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Xiang, Jinjuan AU - Xiang J AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Li, Chen AU - Li C AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Yin, Xiaogen AU - Yin X AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Wang, Xiaolei AU - Wang X AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Yang, Hong AU - Yang H AUID- ORCID: 0000-0003-2860-5901 AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Ma, Xueli AU - Ma X AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Han, Jianghao AU - Han J AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Zhang, Jing AU - Zhang J AD - College of Electronic and Information Engineering, North China University of Technology, Beijing 100144, China. FAU - Hu, Tairan AU - Hu T AD - College of Electronic and Information Engineering, North China University of Technology, Beijing 100144, China. FAU - Cao, Zhe AU - Cao Z AD - College of Electronic and Information Engineering, North China University of Technology, Beijing 100144, China. FAU - Yang, Tao AU - Yang T AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Li, Junfeng AU - Li J AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. FAU - Yin, Huaxiang AU - Yin H AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Zhu, Huilong AU - Zhu H AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Luo, Jun AU - Luo J AUID- ORCID: 0000-0002-5122-6806 AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Wang, Wenwu AU - Wang W AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Radamson, Henry H AU - Radamson HH AD - Key Laboratory of Microelectronics Devices & Integrated Technology, Institute of Microelectronics, Chinese Academy of Sciences, Beijing 100029, China. AD - Microelectronics Institute, University of Chinese Academy of Sciences, Beijing 100049, China. AD - Department of Electronics Design, Mid Sweden University, Holmgatan 10, 85170 Sundsvall, Sweden. LA - eng GR - Y9XDC2X001/advanced C project pre-research of Chinese Academy of Sciences: 3~1 nm integrated circuit advanced process/ GR - without Number/CAS Pioneer Hundred Talents Program/ GR - Z191100010618005/the technology planning project of Beijing/ GR - Z201100004220001/the technology planning project of Beijing/ GR - 2017ZX02315001-002/the National Key Project of Science and Technology of China/ GR - 2016YFA0301701/the National Key Research and Development Program of China/ PT - Journal Article DEP - 20200420 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC7221596 OTO - NOTNLM OT - field effect transistor OT - gate-all-around (GAA) OT - high anisotropy OT - high etch selectivity OT - inner spacer OT - nanosheet OT - nanostructure manufacture OT - nanowire COIS- The authors declare no conflict of interest. EDAT- 2020/04/25 06:00 MHDA- 2020/04/25 06:01 PMCR- 2020/04/20 CRDT- 2020/04/25 06:00 PHST- 2020/03/11 00:00 [received] PHST- 2020/04/15 00:00 [revised] PHST- 2020/04/17 00:00 [accepted] PHST- 2020/04/25 06:00 [entrez] PHST- 2020/04/25 06:00 [pubmed] PHST- 2020/04/25 06:01 [medline] PHST- 2020/04/20 00:00 [pmc-release] AID - nano10040793 [pii] AID - nanomaterials-10-00793 [pii] AID - 10.3390/nano10040793 [doi] PST - epublish SO - Nanomaterials (Basel). 2020 Apr 20;10(4):793. doi: 10.3390/nano10040793.