PMID- 32361015 OWN - NLM STAT- MEDLINE DCOM- 20200716 LR - 20200716 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 254 DP - 2020 Sep TI - Spatial distribution and compositional profiles of organochlorine pesticides in the surface soil from the agricultural, coastal and backwater transects along the south-west coast of India. PG - 126699 LID - S0045-6535(20)30892-4 [pii] LID - 10.1016/j.chemosphere.2020.126699 [doi] AB - South-west coast of India has a history of using pesticidal persistent organic pollutants (POPs) particularly endosulfan until aerial spraying was banned during early 2000. Since soil acts as a repository for such pesticidal persistent organic contaminants, we have monitored residues of seventeen organochlorine pesticides (OCPs) in the surface soil samples from the agricultural, coastal, and backwater transects along the south-west coast of India. OCPs concentration in soil were in the order agricultural > coastal > backwaters transects. Endrins, hexachlorocyclohexane (HCH) and heptachlors were among the dominant OCPs quantified in this study. Dominance of metabolites such as dichlorodiphenyldichloroethylene (DDE), dichlorodiphenyldichloroethane (DDD) and endosulfan sulfate indicates past usage. All the OCPs were dominant in the agricultural transect where plantations/agricultural activities are prevalent. In some specific sites, traces of HCH isomers showed ongoing usage of technical HCH in those sites contradicting the ban in agricultural sector. Backwater sites which are background locations showed positive correlation between soil organic carbon and soil borne OCPs thereby indicating an aged source possibly due to the short/long atmospheric transport from the site of application. Based on the policies regarding control, prevention and other measures for the management of pesticides in Kerala, it was concluded that the implementation on the ground level and the legal framework should be strengthened to prevent further illegal use of the banned pesticides. CI - Copyright (c) 2020 Elsevier Ltd. All rights reserved. FAU - Khuman, Sanjenbam Nirmala AU - Khuman SN AD - Department of Civil Engineering, SRM Research Institute, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu, India. FAU - Vinod, P G AU - Vinod PG AD - GeoVin Solutions (P) Ltd, Kerala, India. FAU - Bharat, Girija AU - Bharat G AD - Mu Gamma Consultants Pvt. Ltd, Gurgaon, India. FAU - Kumar, Y S Mohana AU - Kumar YSM AD - Kumar Clinic.Vaninagar P O, Kasargod, Kerala, India. FAU - Chakraborty, Paromita AU - Chakraborty P AD - Department of Civil Engineering, SRM Research Institute, SRM Institute of Science and Technology, Kattankulathur, Tamil Nadu, India. Electronic address: paromita.c@res.srmuniv.ac.in. LA - eng PT - Journal Article DEP - 20200407 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticides) RN - 0 (Soil) RN - 0 (Soil Pollutants) RN - 4M7FS82U08 (Dichlorodiphenyl Dichloroethylene) RN - 59NEE7PCAB (Hexachlorocyclohexane) RN - 7440-44-0 (Carbon) RN - 8QTV9M19B2 (endosulfan sulfate) RN - OKA6A6ZD4K (Endosulfan) SB - IM MH - Agriculture MH - Carbon MH - Dichlorodiphenyl Dichloroethylene/analysis MH - Endosulfan/analogs & derivatives MH - *Environmental Monitoring MH - Hexachlorocyclohexane MH - Hydrocarbons, Chlorinated/analysis MH - India MH - Pesticides/*analysis MH - Soil/chemistry MH - Soil Pollutants/*analysis OTO - NOTNLM OT - Agricultural OT - Backwaters OT - Coastal OT - Organochlorine pesticides OT - South-west coast EDAT- 2020/05/04 06:00 MHDA- 2020/07/17 06:00 CRDT- 2020/05/04 06:00 PHST- 2020/01/23 00:00 [received] PHST- 2020/03/30 00:00 [revised] PHST- 2020/04/02 00:00 [accepted] PHST- 2020/05/04 06:00 [pubmed] PHST- 2020/07/17 06:00 [medline] PHST- 2020/05/04 06:00 [entrez] AID - S0045-6535(20)30892-4 [pii] AID - 10.1016/j.chemosphere.2020.126699 [doi] PST - ppublish SO - Chemosphere. 2020 Sep;254:126699. doi: 10.1016/j.chemosphere.2020.126699. Epub 2020 Apr 7.