PMID- 32380379 OWN - NLM STAT- MEDLINE DCOM- 20200603 LR - 20200603 IS - 1879-2456 (Electronic) IS - 0956-053X (Linking) VI - 109 DP - 2020 May 15 TI - Fate of heavy metals during co-disposal of municipal solid waste incineration fly ash and sewage sludge by hydrothermal coupling pyrolysis process. PG - 28-37 LID - S0956-053X(20)30216-6 [pii] LID - 10.1016/j.wasman.2020.04.048 [doi] AB - In this work, the hydrothermal coupling pyrolysis (HTP) method was used to treat municipal solid waste incineration fly ash (IFA) and municipal sewage sludge (MSS). The regulation of migration mechanism of heavy metals (HMs), which included Cr, Ni, Cu, Zn, Cd, and Pb, were investigated, including the conditional effects of hydrothermal pretreatment (HTT), the pyrolysis temperature, the pyrolysis time, and the heating rate (HR) on the HM distribution. The results indicated that HTT, as a pretreatment method, achieved the redistribution and preliminary immobilization of the HMs, decreasing the potential environmental risk level. After HTP, the HMs (Cr, Ni, and Cu) were more immobilized, and this effect was enhanced when the pyrolysis temperature was increased from 300 to 800 degrees C. However, Zn, Cd, and Pb evaporated under high temperature. Leaching experiments revealed that all the HMs in the pyro-char from pyrolysis at 800 degrees C were below the standard (US EPA). The influences of the HR and pyrolysis time on the HM immobilization were slight under a higher temperature. After HTP, the HM environmental risk decreased to a low level. The physico-chemical characteristics of the pyro-char demonstrated that carbon trapping and chemical sedimentation played leading roles in the middle-temperature range, while mineral matrix encapsulation might have been dominant under high temperature. CI - Copyright (c) 2020 Elsevier Ltd. All rights reserved. FAU - Chen, Zhan AU - Chen Z AD - CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; University of Chinese Academy of Sciences, Beijing 100049, China. FAU - Yu, Guangwei AU - Yu G AD - CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China. FAU - Wang, Yin AU - Wang Y AD - CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China. Electronic address: yinwang@iue.ac.cn. FAU - Wang, Xingdong AU - Wang X AD - CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China. LA - eng PT - Journal Article DEP - 20200504 PL - United States TA - Waste Manag JT - Waste management (New York, N.Y.) JID - 9884362 RN - 0 (Coal Ash) RN - 0 (Metals, Heavy) RN - 0 (Particulate Matter) RN - 0 (Sewage) RN - 0 (Solid Waste) RN - 7440-44-0 (Carbon) SB - IM MH - Carbon MH - Coal Ash MH - Incineration MH - *Metals, Heavy MH - Particulate Matter MH - Pyrolysis MH - *Refuse Disposal MH - Sewage MH - Solid Waste OTO - NOTNLM OT - Heavy metals OT - Hydrothermal coupling pyrolysis OT - Incineration fly ash OT - Migration mechanism OT - Municipal sewage sludge COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2020/05/08 06:00 MHDA- 2020/06/04 06:00 CRDT- 2020/05/08 06:00 PHST- 2020/01/10 00:00 [received] PHST- 2020/04/10 00:00 [revised] PHST- 2020/04/27 00:00 [accepted] PHST- 2020/05/08 06:00 [pubmed] PHST- 2020/06/04 06:00 [medline] PHST- 2020/05/08 06:00 [entrez] AID - S0956-053X(20)30216-6 [pii] AID - 10.1016/j.wasman.2020.04.048 [doi] PST - ppublish SO - Waste Manag. 2020 May 15;109:28-37. doi: 10.1016/j.wasman.2020.04.048. Epub 2020 May 4.