PMID- 32536151
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200716
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 12
IP  - 28
DP  - 2020 Jul 15
TI  - Super Tough and Self-Healable Poly(dimethylsiloxane) Elastomer via Hydrogen 
      Bonding Association and Its Applications as Triboelectric Nanogenerators.
PG  - 31975-31983
LID - 10.1021/acsami.0c08213 [doi]
AB  - Poly(dimethylsiloxane) (PDMS) as one of the electron-drawing materials has been 
      widely used in triboelectric nanogenerators (TENG), which is expected to generate 
      electron through friction and required to endure dynamic loads. However, the 
      nature of the siloxane bond and the low interchain interaction between the methyl 
      side groups result in low fracture energy in PDMS elastomers. Here, a strategy 
      that combined the advantages of the dynamic of hierarchical hydrogen bonding and 
      phase-separation-like structure was adopted to improve the toughness of PDMS 
      elastomers. By varying both stronger and weaker hydrogen bonding within the PDMS 
      network, a series of super tough (up to 24,000 J/m(2)), notch-insensitive, 
      transparent, and autonomous self-healable elastomers were achieved. In addition, 
      a hydrophilic polymeric material (PDMAS-U10) was synthesized as the conductive 
      layer. A transparent TENG was fabricated by sandwiching the PDMAS-U10 between two 
      pieces of the PDMS elastomer. Despite its hydrophilic nature, PDMAS-U10 exhibit 
      strong adhesion interaction with hydrophobic PDMS elastomers. As such, a tough 
      (16,500 J/m(2)), self-healable (efficiency  approximately 97%), and transparent triboelectric 
      nanogenerator was constructed. A self-powered system employing the TENG is also 
      demonstrated in this work.
FAU - Chen, Haiming
AU  - Chen H
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
FAU - Koh, J Justin
AU  - Koh JJ
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
AD  - Agency for Science, Technology and Research (A*STAR), Singapore Institute of 
      Manufacturing Technology, 73 Nanyang Drive, Singapore 637662, Singapore.
FAU - Liu, Mengmeng
AU  - Liu M
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
FAU - Li, Pengju
AU  - Li P
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
FAU - Fan, Xiaotong
AU  - Fan X
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
FAU - Liu, Siqi
AU  - Liu S
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
FAU - Yeo, Jayven C C
AU  - Yeo JCC
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
FAU - Tan, Yujun
AU  - Tan Y
AUID- ORCID: 0000-0002-3828-9490
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
AD  - Institute for Health Innovation & Technology (iHealthTech), National University 
      of Singapore, 14 Medical Drive, Singapore 117599, Singapore.
FAU - Tee, Benjamin C K
AU  - Tee BCK
AUID- ORCID: 0000-0002-9180-4105
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
AD  - Institute for Health Innovation & Technology (iHealthTech), National University 
      of Singapore, 14 Medical Drive, Singapore 117599, Singapore.
AD  - Institute of Materials Research and Engineering, Agency for Science, Technology, 
      and Research (A*STAR), Innovis, 2 Fusionopolis Way, Singapore 138634, Singapore.
AD  - Department of Electrical and Computer Engineering (ECE), National University of 
      Singapore, Singapore 117583, Singapore.
FAU - He, Chaobin
AU  - He C
AUID- ORCID: 0000-0001-8200-8337
AD  - Department of Materials Science and Engineering, National University of 
      Singapore, 9 Engineering Drive 1, Singapore 117575, Singapore.
AD  - Institute of Materials Research and Engineering, Agency for Science, Technology, 
      and Research (A*STAR), Innovis, 2 Fusionopolis Way, Singapore 138634, Singapore.
LA  - eng
PT  - Journal Article
DEP - 20200629
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - hydrogen bondings
OT  - poly(dimethylsiloxane)
OT  - self-healing
OT  - self-powered system
OT  - tough
OT  - triboelectric nanogenerator
EDAT- 2020/06/17 06:00
MHDA- 2020/06/17 06:01
CRDT- 2020/06/16 06:00
PHST- 2020/06/17 06:00 [pubmed]
PHST- 2020/06/17 06:01 [medline]
PHST- 2020/06/16 06:00 [entrez]
AID - 10.1021/acsami.0c08213 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2020 Jul 15;12(28):31975-31983. doi: 
      10.1021/acsami.0c08213. Epub 2020 Jun 29.