PMID- 32549406
OWN - NLM
STAT- MEDLINE
DCOM- 20210217
LR  - 20221207
IS  - 1422-0067 (Electronic)
IS  - 1422-0067 (Linking)
VI  - 21
IP  - 12
DP  - 2020 Jun 15
TI  - Hybrid Materials Based on Silica Matrices Impregnated with Pt-Porphyrin or PtNPs 
      Destined for CO(2) Gas Detection or for Wastewaters Color Removal.
LID - 10.3390/ijms21124262 [doi]
LID - 4262
AB  - Multifunctional hybrid materials with applications in gas sensing or dye removal 
      from wastewaters were obtained by incorporation into silica matrices of either 
      Pt(II)-5,10,15,20-tetra-(4-allyloxy-phenyl)-porphyrin (PtTAOPP) or platinum 
      nanoparticles (PtNPs) alone or accompanied by 
      5,10,15,20-tetra-(4-allyloxy-phenyl)-porphyrin (TAOPP). The 
      tetraethylorthosilicate (TEOS)-based silica matrices were obtained by using the 
      sol-gel method performed in two step acid-base catalysis. Optical, structural and 
      morphological properties of the hybrid materials were determined and compared by 
      UV-vis, fluorescence and FT-IR spectroscopy techniques, by atomic force 
      microscopy (AFM) and high resolution transmission electron microscopy (HRTEM) and 
      by Brunauer-Emmett-Teller (BET) analysis. PtTAOPP-silica hybrid was the most 
      efficient material both for CO(2) adsorption (0.025 mol/g) and for methylene blue 
      adsorption (7.26 mg/g) from wastewaters. These results were expected due to both 
      the ink-bottle mesopores having large necks that exist in this hybrid material 
      and to the presence of the porphyrin moiety that facilitates chemical 
      interactions with either CO(2) gas or the dye molecule. Kinetic studies 
      concerning the mechanism of dye adsorption demonstrated a second order kinetic 
      model, thus it might be attributed to both physical and chemical processes.
FAU - Anghel, Diana
AU  - Anghel D
AD  - Institute of Chemistry "CoriolanDragulescu" of Romanian Academy, M. Viteazul Ave, 
      No. 24, 300223 Timisoara, Romania.
FAU - Lascu, Anca
AU  - Lascu A
AUID- ORCID: 0000-0002-6081-3324
AD  - Institute of Chemistry "CoriolanDragulescu" of Romanian Academy, M. Viteazul Ave, 
      No. 24, 300223 Timisoara, Romania.
FAU - Epuran, Camelia
AU  - Epuran C
AD  - Institute of Chemistry "CoriolanDragulescu" of Romanian Academy, M. Viteazul Ave, 
      No. 24, 300223 Timisoara, Romania.
FAU - Fratilescu, Ion
AU  - Fratilescu I
AD  - Institute of Chemistry "CoriolanDragulescu" of Romanian Academy, M. Viteazul Ave, 
      No. 24, 300223 Timisoara, Romania.
FAU - Ianasi, Catalin
AU  - Ianasi C
AUID- ORCID: 0000-0002-5137-8164
AD  - Institute of Chemistry "CoriolanDragulescu" of Romanian Academy, M. Viteazul Ave, 
      No. 24, 300223 Timisoara, Romania.
FAU - Birdeanu, Mihaela
AU  - Birdeanu M
AUID- ORCID: 0000-0001-9895-802X
AD  - National Institute for Research and Development in Electrochemistry and Condensed 
      Matter, P. Andronescu Street 1, 300224 Timisoara, Romania.
FAU - Fagadar-Cosma, Eugenia
AU  - Fagadar-Cosma E
AD  - Institute of Chemistry "CoriolanDragulescu" of Romanian Academy, M. Viteazul Ave, 
      No. 24, 300223 Timisoara, Romania.
LA  - eng
GR  - 76PCCDI/2018/Unitatea Executiva pentru Finantarea Invatamantului Superior, a 
      Cercetarii, Dezvoltarii si Inovarii/
GR  - Programe 3-Porphyrins/Institute of Chemistry "Coriolan Dragulescu", formerly The 
      Institute of Chemistry Timisoara of the Romanian Academy/
PT  - Journal Article
DEP - 20200615
PL  - Switzerland
TA  - Int J Mol Sci
JT  - International journal of molecular sciences
JID - 101092791
RN  - 0 (Porphyrins)
RN  - 0 (Waste Water)
RN  - 142M471B3J (Carbon Dioxide)
RN  - 49DFR088MY (Platinum)
RN  - T42P99266K (Methylene Blue)
SB  - IM
MH  - Adsorption
MH  - Biosensing Techniques
MH  - Carbon Dioxide/*analysis
MH  - Metal Nanoparticles
MH  - Methylene Blue/*analysis
MH  - Microscopy, Atomic Force
MH  - Molecular Structure
MH  - Platinum/*chemistry
MH  - Porphyrins/*chemistry
MH  - Spectroscopy, Fourier Transform Infrared
MH  - Wastewater/*analysis
PMC - PMC7352184
OTO - NOTNLM
OT  - Pt-pophyrin
OT  - PtNPs
OT  - silica hybrid materials
OT  - toxic dyes
OT  - wet carbon dioxide adsorption
COIS- The authors declare no conflict of interest.
EDAT- 2020/06/19 06:00
MHDA- 2021/02/18 06:00
PMCR- 2020/06/01
CRDT- 2020/06/19 06:00
PHST- 2020/05/15 00:00 [received]
PHST- 2020/06/06 00:00 [revised]
PHST- 2020/06/15 00:00 [accepted]
PHST- 2020/06/19 06:00 [entrez]
PHST- 2020/06/19 06:00 [pubmed]
PHST- 2021/02/18 06:00 [medline]
PHST- 2020/06/01 00:00 [pmc-release]
AID - ijms21124262 [pii]
AID - ijms-21-04262 [pii]
AID - 10.3390/ijms21124262 [doi]
PST - epublish
SO  - Int J Mol Sci. 2020 Jun 15;21(12):4262. doi: 10.3390/ijms21124262.