PMID- 32559693 OWN - NLM STAT- MEDLINE DCOM- 20200812 LR - 20200812 IS - 1090-2414 (Electronic) IS - 0147-6513 (Linking) VI - 201 DP - 2020 Sep 15 TI - Hybrid carbon nanotubes modified glassy carbon electrode for selective, sensitive and simultaneous detection of dopamine and uric acid. PG - 110872 LID - S0147-6513(20)30711-9 [pii] LID - 10.1016/j.ecoenv.2020.110872 [doi] AB - Based on a hybrid carbon nanotube composite, a novel electrochemical sensor with high sensitivity and selectivity was designed for the simultaneous determination of dopamine (DA) and uric acid (UA). The hybrid carbon nanotube composite was prepared by ultrasonic assembly of carboxylated multi-walled carbon nanotube (MWCNT-COOH) and hydroxylated single-walled carbon nanotube (SWCNT-OH). And the hybrid (MWCNT-COOH/SWCNT-OH) composite was characterized by field emission scanning electron microscopy (FE-SEM) and Fourier transform infrared (FT-IR) spectroscopy. The electrochemical performances of MWCNT-COOH/SWCNT-OH composite modified glassy carbon electrode (MWCNT-COOH/SWCNT-OH/GCE) were analyzed by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse voltammetry (DPV). Under the optimum experimental conditions, the as-prepared sensor showed high sensitivity and selectivity for DA and UA. The calibration curves obtained were linear for the currents versus DA and UA concentrations in the range 2-150 muM, and limits of detection (LODs) were calculated to be 0.37 muM and 0.61 muM (signal-to-noise ratio of 3, S/N = 3), respectively. The recoveries of DA and UA in bovine serum samples at MWCNT-COOH/SWCNT-OH/GCE were in the range 96.18-105.02%, and relative standard deviations (RSDs) were 3.34-7.27%. The proposed electrochemical sensor showed good anti-interference ability, excellent reproducibility and stability, as well as high selectivity, which might provide a promising platform for determination of DA and UA. CI - Copyright (c) 2020 Elsevier Inc. All rights reserved. FAU - Guan, Jin-Feng AU - Guan JF AD - College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, China. FAU - Zou, Jiao AU - Zou J AD - College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, China. FAU - Liu, Yi-Ping AU - Liu YP AD - College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, China. FAU - Jiang, Xin-Yu AU - Jiang XY AD - College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, China. FAU - Yu, Jin-Gang AU - Yu JG AD - College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan, 410083, China. Electronic address: yujg@csu.edu.cn. LA - eng PT - Journal Article DEP - 20200616 PL - Netherlands TA - Ecotoxicol Environ Saf JT - Ecotoxicology and environmental safety JID - 7805381 RN - 0 (Nanotubes, Carbon) RN - 268B43MJ25 (Uric Acid) RN - 7440-44-0 (Carbon) RN - VTD58H1Z2X (Dopamine) SB - IM MH - Animals MH - Carbon MH - Cattle MH - Dopamine/*analysis/blood MH - Electrochemical Techniques/*methods MH - Electrodes MH - Limit of Detection MH - Nanotubes, Carbon/*chemistry/ultrastructure MH - Reproducibility of Results MH - Uric Acid/*analysis/blood OTO - NOTNLM OT - Differential pulse voltammetry OT - Dopamine OT - Electrochemical sensor OT - Multi-walled carbon nanotubes OT - Single-walled carbon nanotubes OT - Uric acid COIS- Declaration of competing interest The authors declare no conflict of interest. EDAT- 2020/06/20 06:00 MHDA- 2020/08/13 06:00 CRDT- 2020/06/20 06:00 PHST- 2020/01/21 00:00 [received] PHST- 2020/04/04 00:00 [revised] PHST- 2020/06/07 00:00 [accepted] PHST- 2020/06/20 06:00 [pubmed] PHST- 2020/08/13 06:00 [medline] PHST- 2020/06/20 06:00 [entrez] AID - S0147-6513(20)30711-9 [pii] AID - 10.1016/j.ecoenv.2020.110872 [doi] PST - ppublish SO - Ecotoxicol Environ Saf. 2020 Sep 15;201:110872. doi: 10.1016/j.ecoenv.2020.110872. Epub 2020 Jun 16.