PMID- 32674672
OWN - NLM
STAT- MEDLINE
DCOM- 20220128
LR  - 20221207
IS  - 1479-487X (Electronic)
IS  - 0959-3330 (Linking)
VI  - 43
IP  - 4
DP  - 2022 Jan
TI  - Degradation of 2,4-dichlorophenol by cathodic microarc plasma electrolysis: 
      characteristics and mechanisms.
PG  - 572-584
LID - 10.1080/09593330.2020.1797896 [doi]
AB  - In this work, we used cathodic microarc plasma electrolysis (CMPE) to degrade 
      2,4-dichlorophenol (2,4-DCP) in simulated wastewater. By investigating and 
      comparing the removal efficiencies and chemical oxygen demand (COD) during the 
      degradation process, higher bath voltage and alkaline condition were considered 
      as more suitable for the 2,4-DCP decomposition. Higher initial 2,4-DCP 
      concentration was attributed to the increase in the utilisation of the energy 
      input. The plasma characteristics during CMPE were studied by optical emission 
      spectroscopy (OES). It was found that the 2,4-DCP directly participated in the 
      plasma discharge process. Furthermore, by studying the evolution of intermediate 
      products at different experimental parameters, it was found that the existence of 
      Cl(-) played an important role in the opening of benzene ring, which activated 
      the ortho-substitutions of hydroxyl, meanwhile accelerated the p-substitutions. 
      The instantaneous high temperature and high pressure and the Cl(-) that were 
      generated and driven by cathodic plasma made the decomposition of 2,4-DCP much 
      quicker.
FAU - Zhang, Yifan
AU  - Zhang Y
AUID- ORCID: 0000-0002-1542-2957
AD  - Key Laboratory of Beam Technology of Ministry of Education, College of Nuclear 
      Science and Technology, Beijing Normal University, Beijing, People's Republic of 
      China.
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
FAU - Yu, Jiahao
AU  - Yu J
AD  - Key Laboratory of Beam Technology of Ministry of Education, College of Nuclear 
      Science and Technology, Beijing Normal University, Beijing, People's Republic of 
      China.
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
FAU - Liu, Guijun
AU  - Liu G
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
FAU - Jin, Xiaoyue
AU  - Jin X
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
FAU - Liu, Ruihong
AU  - Liu R
AD  - Key Laboratory of Beam Technology of Ministry of Education, College of Nuclear 
      Science and Technology, Beijing Normal University, Beijing, People's Republic of 
      China.
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
FAU - Du, Jiancheng
AU  - Du J
AD  - Key Laboratory of Beam Technology of Ministry of Education, College of Nuclear 
      Science and Technology, Beijing Normal University, Beijing, People's Republic of 
      China.
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
FAU - Xue, Wenbin
AU  - Xue W
AUID- ORCID: 0000-0003-1876-8539
AD  - Key Laboratory of Beam Technology of Ministry of Education, College of Nuclear 
      Science and Technology, Beijing Normal University, Beijing, People's Republic of 
      China.
AD  - Beijing Radiation Center, Beijing, People's Republic of China.
LA  - eng
PT  - Journal Article
DEP - 20200731
PL  - England
TA  - Environ Technol
JT  - Environmental technology
JID - 9884939
RN  - 0 (Chlorophenols)
RN  - 0 (Phenols)
RN  - 0 (Waste Water)
RN  - 0 (Water Pollutants, Chemical)
RN  - R669TG1950 (2,4-dichlorophenol)
SB  - IM
MH  - *Chlorophenols
MH  - Electrolysis
MH  - Phenols
MH  - Wastewater
MH  - *Water Pollutants, Chemical
OTO - NOTNLM
OT  - 2,4-DCP degradation
OT  - Cathodic microarc plasma electrolysis
OT  - chloride ion
OT  - degradation mechanism
OT  - efficiency
EDAT- 2020/07/18 06:00
MHDA- 2022/01/29 06:00
CRDT- 2020/07/18 06:00
PHST- 2020/07/18 06:00 [pubmed]
PHST- 2022/01/29 06:00 [medline]
PHST- 2020/07/18 06:00 [entrez]
AID - 10.1080/09593330.2020.1797896 [doi]
PST - ppublish
SO  - Environ Technol. 2022 Jan;43(4):572-584. doi: 10.1080/09593330.2020.1797896. Epub 
      2020 Jul 31.