PMID- 32679978 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200720 IS - 1094-4087 (Electronic) IS - 1094-4087 (Linking) VI - 28 IP - 12 DP - 2020 Jun 8 TI - Quantum cascade laser-based reflectance spectroscopy: a robust approach for the classification of plastic type. PG - 17741-17756 LID - 10.1364/OE.393231 [doi] AB - The identification of plastic type is important for environmental applications ranging from recycling to understanding the fate of plastics in marine, atmospheric, and terrestrial environments. Infrared reflectance spectroscopy is a powerful approach for plastics identification, requiring only optical access to a sample. The use of visible and near-infrared wavelengths for plastics identification are limiting as dark colored plastics absorb at these wavelengths, producing no reflectance spectra. The use of mid-infrared wavelengths instead enables dark plastics to be identified. Here we demonstrate the capability to utilize a pulsed, widely-tunable (5.59 - 7.41 microm) mid-infrared quantum cascade laser, as the source for reflectance spectroscopy, for the rapid and robust identification of plastics. Through the application of linear discriminant analysis to the resulting spectral data set, we demonstrate that we can correctly classify five plastic types: polyethylene terephthalate (PET), high density polyethylene (HDPE), low density polyethylene (LDPE), polypropylene (PP), and polystyrene (PS), with a 97% accuracy rate. FAU - Michel, Anna P M AU - Michel APM FAU - Morrison, Alexandra E AU - Morrison AE FAU - Colson, Beckett C AU - Colson BC FAU - Pardis, William A AU - Pardis WA FAU - Moya, Xavier A AU - Moya XA FAU - Harb, Charles C AU - Harb CC FAU - White, Helen K AU - White HK LA - eng PT - Journal Article PL - United States TA - Opt Express JT - Optics express JID - 101137103 SB - IM EDAT- 2020/07/19 06:00 MHDA- 2020/07/19 06:01 CRDT- 2020/07/19 06:00 PHST- 2020/07/19 06:00 [entrez] PHST- 2020/07/19 06:00 [pubmed] PHST- 2020/07/19 06:01 [medline] AID - 432207 [pii] AID - 10.1364/OE.393231 [doi] PST - ppublish SO - Opt Express. 2020 Jun 8;28(12):17741-17756. doi: 10.1364/OE.393231.