PMID- 32680277 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200720 IS - 1744-6848 (Electronic) IS - 1744-683X (Linking) VI - 2 IP - 10 DP - 2006 Sep 19 TI - Rheo-NMR phenomena of wormlike micelles. PG - 855-869 LID - 10.1039/b600978f [doi] AB - Using a combination of rheology and nuclear magnetic resonance (NMR) spectroscopy/velocimetry we demonstrate the existence of shear banding fluctuations under Couette flow of the micellar system 10% w/v cetylpyridinium chloride and sodium salicylate (CPyCl-NaSal) molar ratio 2 : 1 in 0.5 M NaCl in either HO or HO, using both time-averaged and real-time measurements. These shear banding fluctuations are consistent not only with the shear stress fluctuations observed in rheological measurements but also with fluctuations in the change of the constrained fraction of the amphiphile chain (Delta) observed in H-NMR spectroscopy experiments. Using H-NMR spectroscopy on a deuterated probe molecule (-decane) located in the wormlike micellar interior, direct measurement of the shear-induced nematic phase transition is reported. FAU - Lopez-Gonzalez, M R AU - Lopez-Gonzalez MR AD - MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, P.O. Box 600, New Zealand. FAU - Holmes, W M AU - Holmes WM AD - Wellcome Surgical Institute, University of Glasgow, Glasgow, United KingdomG61 1QH. FAU - Callaghan, P T AU - Callaghan PT AD - MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, P.O. Box 600, New Zealand. LA - eng PT - Journal Article PL - England TA - Soft Matter JT - Soft matter JID - 101295070 SB - IM EDAT- 2006/09/19 00:00 MHDA- 2006/09/19 00:01 CRDT- 2020/07/19 06:00 PHST- 2020/07/19 06:00 [entrez] PHST- 2006/09/19 00:00 [pubmed] PHST- 2006/09/19 00:01 [medline] AID - 10.1039/b600978f [doi] PST - ppublish SO - Soft Matter. 2006 Sep 19;2(10):855-869. doi: 10.1039/b600978f.