PMID- 32727152
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20240329
IS  - 2073-4360 (Electronic)
IS  - 2073-4360 (Linking)
VI  - 12
IP  - 8
DP  - 2020 Jul 27
TI  - PEG/PPG-PDMS-Adamantane-based Crosslinked Terpolymer Using the ROMP Technique to 
      Prepare a Highly Permeable and CO(2)-Selective Polymer Membrane.
LID - 10.3390/polym12081674 [doi]
LID - 1674
AB  - In this study, precursor molecules based on PEG/PPG and polydimethylsiloxane 
      (PDMS), both widely used rubbery polymers, were copolymerized with bulky 
      adamantane into copolymer membranes. Ring-opening metathesis polymerization 
      (ROMP) was employed during the polymerization process to create a structure with 
      both ends crosslinked. The precursor molecules and corresponding polymer 
      membranes were characterized using various analytical methods. The polymer 
      membranes were fabricated using different compositions of PDMS and adamantane, to 
      determine how the network structure affected their gas separation performance. 
      PEG/PPG, in which CO(2) is highly soluble, was copolymerized with PDMS, which has 
      high permeability, and adamantane, which controlled the crosslinking density with 
      a rigid and bulky structure. It was confirmed that the resulting crosslinked 
      polymer membranes exhibited high solubility and diffusivity for CO(2). Further, 
      their crosslinked structure using ROMP technique made it possible to form good 
      films. The membranes fabricated in the present study exhibited excellent 
      performance, i.e., CO(2) permeability of up to 514.5 Barrer and CO(2)/N(2) 
      selectivity of 50.9.
FAU - Kim, Dongyoung
AU  - Kim D
AD  - Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National 
      University, 119 Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
AD  - Research Institute of Basic Sciences, Incheon National University, 119 
      Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
FAU - Hossain, Iqubal
AU  - Hossain I
AUID- ORCID: 0000-0002-1363-8527
AD  - Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National 
      University, 119 Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
AD  - Research Institute of Basic Sciences, Incheon National University, 119 
      Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
FAU - Kim, Yeonho
AU  - Kim Y
AD  - Research Institute of Basic Sciences, Incheon National University, 119 
      Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
FAU - Choi, Ook
AU  - Choi O
AD  - Research Institute of Basic Sciences, Incheon National University, 119 
      Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
FAU - Kim, Tae-Hyun
AU  - Kim TH
AUID- ORCID: 0000-0002-1654-3785
AD  - Organic Material Synthesis Laboratory, Department of Chemistry, Incheon National 
      University, 119 Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
AD  - Research Institute of Basic Sciences, Incheon National University, 119 
      Academy-ro, Yeonsu-gu, Incheon 22012, Korea.
LA  - eng
GR  - 2017R1A6A1A06015181/National Research Foundation of Korea (NRF)/
GR  - Research Assistance Program (2020)/Incheon National University/
PT  - Journal Article
DEP - 20200727
PL  - Switzerland
TA  - Polymers (Basel)
JT  - Polymers
JID - 101545357
PMC - PMC7464022
OTO - NOTNLM
OT  - CO2 separation
OT  - adamantane
OT  - polymer membrane
OT  - ring-opening metathesis polymerization
OT  - rubbery polymer
COIS- The authors declare no conflict of interest.
EDAT- 2020/07/31 06:00
MHDA- 2020/07/31 06:01
PMCR- 2020/07/27
CRDT- 2020/07/31 06:00
PHST- 2020/07/11 00:00 [received]
PHST- 2020/07/23 00:00 [revised]
PHST- 2020/07/24 00:00 [accepted]
PHST- 2020/07/31 06:00 [entrez]
PHST- 2020/07/31 06:00 [pubmed]
PHST- 2020/07/31 06:01 [medline]
PHST- 2020/07/27 00:00 [pmc-release]
AID - polym12081674 [pii]
AID - polymers-12-01674 [pii]
AID - 10.3390/polym12081674 [doi]
PST - epublish
SO  - Polymers (Basel). 2020 Jul 27;12(8):1674. doi: 10.3390/polym12081674.