PMID- 32798814 OWN - NLM STAT- MEDLINE DCOM- 20201208 LR - 20201214 IS - 1873-7072 (Electronic) IS - 0308-8146 (Linking) VI - 338 DP - 2021 Feb 15 TI - A magnetic fluorinated multi-walled carbon nanotubes-based QuEChERS method for organophosphorus pesticide residues analysis in Lycium ruthenicum Murr. PG - 127805 LID - S0308-8146(20)31667-8 [pii] LID - 10.1016/j.foodchem.2020.127805 [doi] AB - In order to meet the requirements of pesticide residues' detection in complex matrix samples, the magnetic fluorinated multi-wall carbon nanotubes (M-F-MWCNTs) were prepared and applied as new QuEChERS clean-up materials. Combined with GC-MS, an improved QuEChERS method was successfully developed for the detection of organophosphorus pesticide residues. The results showed that the M-F-MWCNTs could effectively remove the interfering substances in Lycium ruthenicum Murr. (L. ruthenicum) samples. The recoveries of 10 tested targets were 74.9% to 113.5% with the relative standard deviations (RSDs) of 3.9-14.7%. The experiment results pointed out that the M-F-MWCNTs were qualified as QuEChERS clean-up materials and expected to be applied to other complex matrix samples and pesticide targets. CI - Copyright (c) 2020 Elsevier Ltd. All rights reserved. FAU - Wang, Jun AU - Wang J AD - Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province and Key Laboratory of Medicinal Resources and Natural Pharmaceutical Chemistry of the Ministry of Education, Shaanxi Normal University, Xi'an 710062, China; Institute of Agricultural Product Quality Standard and Testing Research, Tibet Academy of Agricultural and Animal Husbandry Sciences, Lhasa 850032, China. FAU - Duan, Hui-Ling AU - Duan HL AD - Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province and Key Laboratory of Medicinal Resources and Natural Pharmaceutical Chemistry of the Ministry of Education, Shaanxi Normal University, Xi'an 710062, China. FAU - Fan, Li AU - Fan L AD - Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province and Key Laboratory of Medicinal Resources and Natural Pharmaceutical Chemistry of the Ministry of Education, Shaanxi Normal University, Xi'an 710062, China. FAU - Zhang, Jing AU - Zhang J AD - Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province and Key Laboratory of Medicinal Resources and Natural Pharmaceutical Chemistry of the Ministry of Education, Shaanxi Normal University, Xi'an 710062, China. FAU - Zhang, Zhi-Qi AU - Zhang ZQ AD - Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province and Key Laboratory of Medicinal Resources and Natural Pharmaceutical Chemistry of the Ministry of Education, Shaanxi Normal University, Xi'an 710062, China. Electronic address: zqzhang@snnu.edu.cn. LA - eng PT - Journal Article DEP - 20200809 PL - England TA - Food Chem JT - Food chemistry JID - 7702639 RN - 0 (Nanotubes, Carbon) RN - 0 (Organophosphates) RN - 0 (Pesticide Residues) RN - 284SYP0193 (Fluorine) SB - IM MH - Fluorine/chemistry MH - Food Analysis/instrumentation/*methods MH - Food Contamination/*analysis MH - Gas Chromatography-Mass Spectrometry/methods MH - Limit of Detection MH - Lycium/*chemistry MH - Magnetic Phenomena MH - Nanotubes, Carbon/*chemistry MH - Organophosphates/analysis MH - Pesticide Residues/*analysis OTO - NOTNLM OT - Clean-up materials OT - Magnetic fluorinated multi-wall carbon nanotubes OT - Pesticide residues OT - QuEChERS COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2020/08/18 06:00 MHDA- 2020/12/15 06:00 CRDT- 2020/08/18 06:00 PHST- 2020/02/26 00:00 [received] PHST- 2020/08/07 00:00 [revised] PHST- 2020/08/07 00:00 [accepted] PHST- 2020/08/18 06:00 [pubmed] PHST- 2020/12/15 06:00 [medline] PHST- 2020/08/18 06:00 [entrez] AID - S0308-8146(20)31667-8 [pii] AID - 10.1016/j.foodchem.2020.127805 [doi] PST - ppublish SO - Food Chem. 2021 Feb 15;338:127805. doi: 10.1016/j.foodchem.2020.127805. Epub 2020 Aug 9.