PMID- 32875671
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20201007
IS  - 1521-4095 (Electronic)
IS  - 0935-9648 (Linking)
VI  - 32
IP  - 40
DP  - 2020 Oct
TI  - Three-Phase Boundary in Cross-Coupled Micro-Mesoporous Networks Enabling 
      3D-Printed and Ionogel-Based Quasi-Solid-State Micro-Supercapacitors.
PG  - e2002474
LID - 10.1002/adma.202002474 [doi]
AB  - The construction of advanced micro-supercapacitors (MSCs) with both wide 
      working-voltage and high energy density is promising but still challenging. In 
      this work, a series of nitrogen-doped, cross-coupled micro-mesoporous 
      carbon-metal networks (N-STC/M(x) O(y) ) is developed as robust additives to 3D 
      printing inks for MSCs fabrication. Taking the N-STC/Fe(2) O(3) nanocomposite as 
      an example, both experimental results and theoretical simulations reveal that the 
      well-developed hierarchical networks with abundantly decorated ultrafine Fe(2) 
      O(3) nanoparticles not only significantly facilitate the ion adsorption at its 
      three-phase boundaries (Fe(2) O(3) , N-STC, and electrolyte), but also greatly 
      favor ionic diffusion/transport with shortened pathways. Consequently, the 
      as-prepared N-STC/Fe(2) O(3) electrode delivers a high gravimetric capacitance 
      (267 F g(-1) at 2 mV s(-1) ) and outstanding stability in a 
      liquid-electrolyte-based symmetric device, as well as a record-high energy 
      density of 114 Wh kg(-1) for an asymmetric supercapacitor. Particularly, the 
      gravimetric capacitance of the ionogel-based quasi-solid-state MSCs by 3D 
      printing reaches 377 F g(-1) and the device can operate under a wide temperature 
      range (-10 to 60  degrees C).
CI  - (c) 2020 Wiley-VCH GmbH.
FAU - Lai, Feili
AU  - Lai F
AD  - The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, 
      School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, 
      P. R. China.
AD  - Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 
      Leuven, 3001, Belgium.
FAU - Yang, Chao
AU  - Yang C
AD  - Institute of Materials Science and Technology, Technische Universitat Berlin, 
      Strasse des 17. Juni, Berlin, 10623, Germany.
FAU - Lian, Ruqian
AU  - Lian R
AD  - The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, 
      School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, 
      P. R. China.
FAU - Chu, Kaibin
AU  - Chu K
AD  - The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, 
      School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, 
      P. R. China.
FAU - Qin, Jingjing
AU  - Qin J
AD  - The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, 
      School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, 
      P. R. China.
FAU - Zong, Wei
AU  - Zong W
AD  - The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, 
      School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, 
      P. R. China.
FAU - Rao, Dewei
AU  - Rao D
AD  - School of Materials Science and Engineering, Jiangsu University, Zhenjiang, 
      212013, P. R. China.
FAU - Hofkens, Johan
AU  - Hofkens J
AD  - Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, 
      Leuven, 3001, Belgium.
AD  - Max Planck Institute for Polymer Research, Ackermannweg 10, Mainz, 55128, 
      Germany.
FAU - Lu, Xihong
AU  - Lu X
AUID- ORCID: 0000-0002-6764-0024
AD  - MOE of the Key Laboratory of Bioinorganic and Synthetic Chemistry, The Key Lab of 
      Low-carbon Chem and Energy Conservation of Guangdong Province, School of 
      Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.
FAU - Liu, Tianxi
AU  - Liu T
AD  - The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, 
      School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, 
      P. R. China.
LA  - eng
GR  - 51433001/National Natural Science Foundation of China/
GR  - 21674019/National Natural Science Foundation of China/
GR  - 18JC1410600/Shanghai Scientific and Technological Innovation Project/
GR  - 17XD1400100/Program of Shanghai Academic Research Leader/
PT  - Journal Article
DEP - 20200902
PL  - Germany
TA  - Adv Mater
JT  - Advanced materials (Deerfield Beach, Fla.)
JID - 9885358
SB  - IM
OTO - NOTNLM
OT  - 3D printing
OT  - Fe2O3
OT  - carbon
OT  - ionic liquids
OT  - micro-supercapacitors
EDAT- 2020/09/03 06:00
MHDA- 2020/09/03 06:01
CRDT- 2020/09/03 06:00
PHST- 2020/04/11 00:00 [received]
PHST- 2020/08/02 00:00 [revised]
PHST- 2020/09/03 06:00 [pubmed]
PHST- 2020/09/03 06:01 [medline]
PHST- 2020/09/03 06:00 [entrez]
AID - 10.1002/adma.202002474 [doi]
PST - ppublish
SO  - Adv Mater. 2020 Oct;32(40):e2002474. doi: 10.1002/adma.202002474. Epub 2020 Sep 
      2.