PMID- 32880164
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20201002
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 12
IP  - 39
DP  - 2020 Sep 30
TI  - Ultrafast and Highly Sensitive Chemically Functionalized Graphene Oxide-Based 
      Humidity Sensors: Harnessing Device Performances via the Supramolecular Approach.
PG  - 44017-44025
LID - 10.1021/acsami.0c11236 [doi]
AB  - Humidity sensors have been gaining increasing attention because of their 
      relevance for well-being. To meet the ever-growing demand for new cost-efficient 
      materials with superior performances, graphene oxide (GO)-based relative humidity 
      sensors have emerged recently as low-cost and highly sensitive devices. However, 
      current GO-based sensors suffer from important drawbacks including slow response 
      and recovery, as well as poor stability. Interestingly, reduced GO (rGO) exhibits 
      higher stability, yet accompanied by a lower sensitivity to humidity due to its 
      hydrophobic nature. With the aim of improving the sensing performances of rGO, 
      here we report on a novel generation of humidity sensors based on a simple 
      chemical modification of rGO with hydrophilic moieties, i.e., triethylene glycol 
      chains. Such a hybrid material exhibits an outstandingly improved sensing 
      performance compared to pristine rGO such as high sensitivity (31% increase in 
      electrical resistance when humidity is shifted from 2 to 97%), an ultrafast 
      response (25 ms) and recovery in the subsecond timescale, low hysteresis (1.1%), 
      excellent repeatability and stability, as well as high selectivity toward 
      moisture. Such highest-key-performance indicators demonstrate the full potential 
      of two-dimensional (2D) materials when decorated with suitably designed 
      supramolecular receptors to develop the next generation of chemical sensors of 
      any analyte of interest.
FAU - Anichini, Cosimo
AU  - Anichini C
AD  - Universite de Strasbourg, CNRS, ISIS, 8 allee Gaspard Monge, 67000 Strasbourg, 
      France.
FAU - Aliprandi, Alessandro
AU  - Aliprandi A
AD  - Universite de Strasbourg, CNRS, ISIS, 8 allee Gaspard Monge, 67000 Strasbourg, 
      France.
FAU - Gali, Sai Manoj
AU  - Gali SM
AD  - CMN, Universite de Mons, Place du Parc 20, 7000 Mons, Belgium.
FAU - Liscio, Fabiola
AU  - Liscio F
AD  - Istituto per la Microelettronica e Microsistemi (IMM)-CNR, via Gobetti 101, 40129 
      Bologna, Italy.
FAU - Morandi, Vittorio
AU  - Morandi V
AUID- ORCID: 0000-0002-8533-1540
AD  - Istituto per la Microelettronica e Microsistemi (IMM)-CNR, via Gobetti 101, 40129 
      Bologna, Italy.
FAU - Minoia, Andrea
AU  - Minoia A
AD  - CMN, Universite de Mons, Place du Parc 20, 7000 Mons, Belgium.
FAU - Beljonne, David
AU  - Beljonne D
AUID- ORCID: 0000-0002-2989-3557
AD  - CMN, Universite de Mons, Place du Parc 20, 7000 Mons, Belgium.
FAU - Ciesielski, Artur
AU  - Ciesielski A
AUID- ORCID: 0000-0003-3542-4092
AD  - Universite de Strasbourg, CNRS, ISIS, 8 allee Gaspard Monge, 67000 Strasbourg, 
      France.
FAU - Samori, Paolo
AU  - Samori P
AUID- ORCID: 0000-0001-6256-8281
AD  - Universite de Strasbourg, CNRS, ISIS, 8 allee Gaspard Monge, 67000 Strasbourg, 
      France.
LA  - eng
PT  - Journal Article
DEP - 20200916
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - chemical functionalization
OT  - chemical sensing
OT  - graphene oxide
OT  - humidity sensing
OT  - supramolecular chemistry
EDAT- 2020/09/04 06:00
MHDA- 2020/09/04 06:01
CRDT- 2020/09/04 06:00
PHST- 2020/09/04 06:00 [pubmed]
PHST- 2020/09/04 06:01 [medline]
PHST- 2020/09/04 06:00 [entrez]
AID - 10.1021/acsami.0c11236 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2020 Sep 30;12(39):44017-44025. doi: 
      10.1021/acsami.0c11236. Epub 2020 Sep 16.