PMID- 32980997 OWN - NLM STAT- MEDLINE DCOM- 20210727 LR - 20210727 IS - 1436-5073 (Electronic) IS - 0026-3672 (Linking) VI - 187 IP - 10 DP - 2020 Sep 26 TI - Bi, Fe, and Ti ternary co-doped ZrO(2) nanocomposites as a mass spectrometry matrix for the determination of bisphenol A and tetrabromobisphenol A in tea. PG - 582 LID - 10.1007/s00604-020-04544-9 [doi] AB - Bi, Fe, and Ti ternary co-doped ZrO(2) (BFT-ZrO(2)) nanocomposites have been prepared by a sol-gel process and used as both adsorbent and matrix for the enrichment and determination of small molecules by surface-enhanced laser desorption/ionization time-of-flight mass spectrometry (SELDI-TOF MS). The BFT-ZrO(2) nanocomposites not only can selectively enrich a wide variety of low-mass toxic pollutants but can also be used as an excellent matrix to enhance the laser desorption/ionization efficiency with low background noise and uniform co-crystalline film. Low limits of detection (LODs) (0.1 pg mL(-1) for bisphenol A (BPA), 2 pg mL(-1) for tetrabromobisphenol A (TBBPA), 0.1 pg mL(-1) for alizarin (AZ), 0.001 pg mL(-1)for bisphenol S (BPS), 0.01 pg mL(-1) for indigo blue (ID), 0.01 pg mL(-1) for pentachlorophenol (PCP), 100 pg mL(-1) for estradiol (E2), 0.001 pg mL(-1) for cetyltrimethylammonium bromide (CTAB), 0.1 pg mL(-1) for crystal violet (CV), 1 pg mL(-1) for malachite green (MG), 0.01 pg mL(-1) for rhodamine B (RhB), and 0.01 pg mL(-1) for perfluorooctane sulfonate (PFOS) were achieved. The relative standard deviations (RSDs) of shot-to-shot are 9.4-24% and of sample-to-sample 5.2-17%. The BFT-ZrO(2) matrix was successfully applied to the determination of TBBPA and BPA in tea samples. This method shows a new strategy for determination of toxic compounds in tea. Graphical abstract. FAU - Zhen, Deshuai AU - Zhen D AD - State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People's Republic of China. AD - School of Public Health, University of South China, Hengyang, 421001, People's Republic of China. FAU - Shi, Sisi AU - Shi S AD - State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People's Republic of China. FAU - Gao, Chan AU - Gao C AD - State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People's Republic of China. FAU - Kang, Qing AU - Kang Q AD - Institute of Surface Analysis and Chemical Biology, University of Jinan, Jinan, 250022, Shandong, People's Republic of China. FAU - Xiao, Xilin AU - Xiao X AD - School of Public Health, University of South China, Hengyang, 421001, People's Republic of China. 631295316@qq.com. FAU - Grimes, Craig A AU - Grimes CA AD - State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People's Republic of China. FAU - Cai, Qingyun AU - Cai Q AUID- ORCID: 0000-0002-0867-5905 AD - State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People's Republic of China. caigroup@126.com. LA - eng GR - 21874038, 21802051/National Natural Science Foundation of China/International PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20200926 PL - Austria TA - Mikrochim Acta JT - Mikrochimica acta JID - 7808782 RN - 0 (Benzhydryl Compounds) RN - 0 (Phenols) RN - 0 (Tea) RN - D1JT611TNE (Titanium) RN - MLT3645I99 (bisphenol A) SB - IM MH - Benzhydryl Compounds/*chemistry MH - Nanocomposites/*chemistry MH - Phenols/*chemistry MH - Tandem Mass Spectrometry/*methods MH - Tea/*chemistry MH - Titanium/*chemistry OTO - NOTNLM OT - BFT-ZrO2 OT - Bisphenol A OT - Mass spectrometry OT - Nanocomposites OT - Tea analysis OT - Tetrabromobisphenol A OT - Toxic contaminants EDAT- 2020/09/28 06:00 MHDA- 2021/07/28 06:00 CRDT- 2020/09/27 20:37 PHST- 2020/03/19 00:00 [received] PHST- 2020/09/02 00:00 [accepted] PHST- 2020/09/27 20:37 [entrez] PHST- 2020/09/28 06:00 [pubmed] PHST- 2021/07/28 06:00 [medline] AID - 10.1007/s00604-020-04544-9 [pii] AID - 10.1007/s00604-020-04544-9 [doi] PST - epublish SO - Mikrochim Acta. 2020 Sep 26;187(10):582. doi: 10.1007/s00604-020-04544-9.