PMID- 33074662
OWN - NLM
STAT- MEDLINE
DCOM- 20210310
LR  - 20210310
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 12
IP  - 43
DP  - 2020 Oct 28
TI  - High-Performance Flexible Electrochemical Heavy Metal Sensor Based on 
      Layer-by-Layer Assembly of Ti(3)C(2)T(x)/MWNTs Nanocomposites for Noninvasive 
      Detection of Copper and Zinc Ions in Human Biofluids.
PG  - 48928-48937
LID - 10.1021/acsami.0c12239 [doi]
AB  - A flexible electrochemical heavy metal sensor based on a gold (Au) electrode 
      modified with layer-by-layer (LBL) assembly of titanium carbide (Ti(3)C(2)T(x)) 
      and multiwalled carbon nanotubes (MWNTs) nanocomposites was successfully 
      fabricated for the detection of copper (Cu) and zinc (Zn) ions. An LBL 
      drop-coating process was adopted to modify the surface of Au electrodes with 
      Ti(3)C(2)T(x)/MWNTs treated via ultrasonication to fabricate this novel 
      nanocomposite electrode. In addition, an in situ simultaneous deposition of 
      "green metal" antimony (Sb) and target analytes was performed to improve the 
      detection performance further. The electrochemical measurement was realized using 
      square wave anodic stripping voltammetry (SWASV). Moreover, the fabricated sensor 
      exhibited excellent detection performance under the optimal experimental 
      conditions. The detection limits for Cu and Zn are as low as 0.1 and 1.5 ppb, 
      respectively. Furthermore, Cu and Zn ions were successfully detected in 
      biofluids, that is, urine and sweat, in a wide range of concentration (urine Cu: 
      10-500 ppb; urine Zn: 200-600 ppb; sweat Cu: 300-1500 ppb; and sweat Zn: 500-1500 
      ppb). The fabricated flexible sensor also possesses other advantages of 
      ultra-repeatability and excellent stability. Thus, these advantages provide a 
      great possibility for the noninvasive smart monitoring of heavy metals in the 
      future.
FAU - Hui, Xue
AU  - Hui X
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Sharifuzzaman, Md
AU  - Sharifuzzaman M
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Sharma, Sudeep
AU  - Sharma S
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Xuan, Xing
AU  - Xuan X
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Zhang, Shipeng
AU  - Zhang S
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Ko, Seok Gyu
AU  - Ko SG
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Yoon, Sang Hyuk
AU  - Yoon SH
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
FAU - Park, Jae Yeong
AU  - Park JY
AUID- ORCID: 0000-0002-2056-5151
AD  - Advanced Sensor and Energy Research (ASER) Laboratory, Department of Electronic 
      Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
LA  - eng
PT  - Journal Article
DEP - 20201019
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
RN  - 0 (Ions)
RN  - 0 (Nanotubes, Carbon)
RN  - 12070-08-5 (titanium carbide)
RN  - 789U1901C5 (Copper)
RN  - D1JT611TNE (Titanium)
RN  - J41CSQ7QDS (Zinc)
SB  - IM
MH  - Biosensing Techniques
MH  - Copper/*urine
MH  - *Electrochemical Techniques
MH  - Ions/urine
MH  - Nanocomposites/*chemistry
MH  - Nanotubes, Carbon/*chemistry
MH  - Particle Size
MH  - Surface Properties
MH  - Sweat/chemistry
MH  - Titanium/*chemistry
MH  - Zinc/*urine
OTO - NOTNLM
OT  - Ti3C2Tx-MXene
OT  - flexible sensor
OT  - heavy metal detection
OT  - human biofluids
OT  - layer-by-layer nanocomposites
OT  - multiwalled carbon nanotubes
EDAT- 2020/10/20 06:00
MHDA- 2021/03/11 06:00
CRDT- 2020/10/19 17:10
PHST- 2020/10/20 06:00 [pubmed]
PHST- 2021/03/11 06:00 [medline]
PHST- 2020/10/19 17:10 [entrez]
AID - 10.1021/acsami.0c12239 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2020 Oct 28;12(43):48928-48937. doi: 
      10.1021/acsami.0c12239. Epub 2020 Oct 19.