PMID- 33121047 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201128 IS - 2304-8158 (Print) IS - 2304-8158 (Electronic) IS - 2304-8158 (Linking) VI - 9 IP - 11 DP - 2020 Oct 27 TI - Comparison of Pesticide Residue Levels in Red Wines from Canary Islands, Iberian Peninsula, and Cape Verde. LID - 10.3390/foods9111555 [doi] LID - 1555 AB - In this work, the QuEChERS method coupled to liquid chromatography-time-of flight-mass spectrometry and gas chromatography-triple quadrupole-mass spectrometry were applied for the evaluation of pesticide residues and risk assessment in red wines. The methodologies were successfully validated for 173 pesticides. Recovery values were in the range 75-100% for almost all pesticides and limits of quantification were between 2.60 and 21.39 microg/kg, which are in good agreement with the maximum residue limits (MRLs) established by the European Commission for pesticides in wine grapes. Finally, the analysis of 84 red wine samples from the Canary Islands, the Iberian Peninsula, and Cape Verde was carried out, which found the presence of 31 pesticide residues. However, the risk assessment disclosed that despite the large number of pesticides and the concentrations found, which in some cases exceeded the MRLs, the consumption of these wines, without considering a possible cumulative effect, does not entail a risk to the consumers. FAU - Santana-Mayor, Alvaro AU - Santana-Mayor A AD - Departamento de Quimica, Unidad Departamental de Quimica Analitica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez, s/n. 38206 San Cristobal de La Laguna, Tenerife, Spain. FAU - Rodriguez-Ramos, Ruth AU - Rodriguez-Ramos R AD - Departamento de Quimica, Unidad Departamental de Quimica Analitica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez, s/n. 38206 San Cristobal de La Laguna, Tenerife, Spain. FAU - Socas-Rodriguez, Barbara AU - Socas-Rodriguez B AUID- ORCID: 0000-0002-8396-933X AD - Laboratory of Foodomics, Institute of Food Science Research, CIAL, CSIC, Nicolas Cabrera 9, 28049 Madrid, Spain. FAU - Diaz-Romero, Carlos AU - Diaz-Romero C AD - Departamento de Ingenieria Quimica y Tecnologia Farmaceutica, Unidad Departamental de Nutricion y Bromatologia, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez, s/n. 38206 San Cristobal de La Laguna, Tenerife, Spain. FAU - Rodriguez-Delgado, Miguel Angel AU - Rodriguez-Delgado MA AD - Departamento de Quimica, Unidad Departamental de Quimica Analitica, Facultad de Ciencias, Universidad de La Laguna (ULL), Avenida Astrofisico Francisco Sanchez, s/n. 38206 San Cristobal de La Laguna, Tenerife, Spain. LA - eng GR - Mac/1.1a/049/European Commission/ PT - Journal Article DEP - 20201027 PL - Switzerland TA - Foods JT - Foods (Basel, Switzerland) JID - 101670569 PMC - PMC7694142 OTO - NOTNLM OT - Macaronesia OT - Spain OT - agricultural contamination OT - alcoholic beverages OT - organic contaminants OT - pesticide occurrence COIS- Authors declare no conflict of interest. EDAT- 2020/10/31 06:00 MHDA- 2020/10/31 06:01 PMCR- 2020/10/27 CRDT- 2020/10/30 01:02 PHST- 2020/10/06 00:00 [received] PHST- 2020/10/16 00:00 [revised] PHST- 2020/10/21 00:00 [accepted] PHST- 2020/10/30 01:02 [entrez] PHST- 2020/10/31 06:00 [pubmed] PHST- 2020/10/31 06:01 [medline] PHST- 2020/10/27 00:00 [pmc-release] AID - foods9111555 [pii] AID - foods-09-01555 [pii] AID - 10.3390/foods9111555 [doi] PST - epublish SO - Foods. 2020 Oct 27;9(11):1555. doi: 10.3390/foods9111555.