PMID- 33151456
OWN - NLM
STAT- MEDLINE
DCOM- 20201109
LR  - 20201216
IS  - 1573-2959 (Electronic)
IS  - 0167-6369 (Linking)
VI  - 192
IP  - 12
DP  - 2020 Nov 5
TI  - Sorption behavior of selected chlorophenols onto polyurethane foam treated with 
      iron(III): kinetics and thermodynamic study.
PG  - 748
LID - 10.1007/s10661-020-08693-5 [doi]
AB  - An efficient, selective, and inexpensive method for complete elimination of 
      chlorophenols (CPs) from water has been established. The proposed procedure was 
      based upon the use of n-tributyl phosphate (TBP)-plasticized iron(III) physically 
      immobilized polyurethane foam (PUF) solid sorbent for complete removal of CPs 
      from aqueous media at pH close to 0. The interaction of the complex ion 
      [Fe(C(6)H(5)O)(6)](3-) with protonated ether oxygen of the PUF sorbent forms 
      ternary ion associate on/in the PUFs. The retention of 4-chlorophenol (4-C) and 
      2,4,6-trichlorophenol (TCP) by the TBP-treated iron(III)-immobilized PUF fitted 
      well with the pseudo-second-order kinetic model with a rate constant (k) of 0.04 
      and 0.15 g (mg min)(-1), respectively. The sorption of 4-CP was endothermic 
      whereas the uptake of TCP was favorable at low temperature approving the 
      exothermic and non-spontaneous characteristics of its uptake. The DeltaS value for 
      4-CP reveals good affinity of the ion [Fe(C(6)H(5)O)(6)](3-) towards the PUF 
      sorbent.
FAU - Saigl, Z M
AU  - Saigl ZM
AD  - Department of Chemistry, Faculty of Science, King Abdulaziz University, P.O. Box 
      80203, Jeddah, 21589, Saudi Arabia. zsaigl@kau.edu.sa.
LA  - eng
PT  - Journal Article
DEP - 20201105
PL  - Netherlands
TA  - Environ Monit Assess
JT  - Environmental monitoring and assessment
JID - 8508350
RN  - 0 (Chlorophenols)
RN  - 0 (Polyurethanes)
RN  - 0 (Water Pollutants, Chemical)
RN  - 9009-54-5 (polyurethane foam)
RN  - E1UOL152H7 (Iron)
SB  - IM
MH  - Adsorption
MH  - *Chlorophenols
MH  - Environmental Monitoring
MH  - Hydrogen-Ion Concentration
MH  - Iron
MH  - Kinetics
MH  - Polyurethanes
MH  - Thermodynamics
MH  - *Water Pollutants, Chemical
OTO - NOTNLM
OT  - Chlorophenols
OT  - Environmental water sample
OT  - Plasticized polyurethane foam
OT  - Pseudo-second order
OT  - Retention
OT  - Thermodynamic
EDAT- 2020/11/06 06:00
MHDA- 2020/11/11 06:00
CRDT- 2020/11/05 12:14
PHST- 2020/02/28 00:00 [received]
PHST- 2020/10/18 00:00 [accepted]
PHST- 2020/11/05 12:14 [entrez]
PHST- 2020/11/06 06:00 [pubmed]
PHST- 2020/11/11 06:00 [medline]
AID - 10.1007/s10661-020-08693-5 [pii]
AID - 10.1007/s10661-020-08693-5 [doi]
PST - epublish
SO  - Environ Monit Assess. 2020 Nov 5;192(12):748. doi: 10.1007/s10661-020-08693-5.