PMID- 33189327 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20210104 LR - 20210104 IS - 1095-7103 (Electronic) IS - 0021-9797 (Linking) VI - 586 DP - 2021 Mar 15 TI - Surface modification of zero-valent iron nanoparticles with beta-cyclodextrin for 4-nitrophenol conversion. PG - 655-662 LID - S0021-9797(20)31475-2 [pii] LID - 10.1016/j.jcis.2020.10.135 [doi] AB - Environmental pollution causes irreversible damage to ecosystems and their structure. Therefore, the development of novel remedial techniques is a must for an effective response to emerging contaminants and those already persisting in the environment. The nanosized zero-valent iron (nZVI) is considered as an important nanostructure for the degradation of toxic compounds. Furthermore, the degradative potential of nZVI may be improved by surface modification. In this work nZVI was functionalized with beta-cyclodextrin (beta-CD), which is considered to be an environmentally-friendly and cheap adsorbent for toxic pollutants. Such a 'green' improvement not only enhances the activity of nZVI but also enables the conversion of 4-nitrophenol to 4-aminophenol, which under standard conditions is persistent and does not significantly react with bare nZVI. This research may help to find a solution to treat persistent organic pollutants (POPs) in aqueous environment. CI - Copyright (c) 2020 Elsevier Inc. All rights reserved. FAU - Krawczyk, Kamil AU - Krawczyk K AD - Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentska 1402/2, 461 17, Liberec 1, EU, Czech Republic. FAU - Waclawek, Stanislaw AU - Waclawek S AD - Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentska 1402/2, 461 17, Liberec 1, EU, Czech Republic. Electronic address: stanislaw.waclawek@tul.cz. FAU - Silvestri, Daniele AU - Silvestri D AD - Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentska 1402/2, 461 17, Liberec 1, EU, Czech Republic. FAU - Padil, Vinod V T AU - Padil VVT AD - Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentska 1402/2, 461 17, Liberec 1, EU, Czech Republic. FAU - Rezanka, Michal AU - Rezanka M AD - Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentska 1402/2, 461 17, Liberec 1, EU, Czech Republic. FAU - Cernik, Miroslav AU - Cernik M AD - Institute for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentska 1402/2, 461 17, Liberec 1, EU, Czech Republic. FAU - Jaroniec, Mietek AU - Jaroniec M AD - Department of Chemistry and Biochemistry & Advanced Materials and Liquid Crystal Institute, Kent State University, Kent, OH 44242, USA. Electronic address: jaroniec@kent.edu. LA - eng PT - Journal Article DEP - 20201103 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 SB - IM OTO - NOTNLM OT - Cyclodextrins OT - Modified particles OT - Water and wastewater treatment OT - Zero-valent iron COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2020/11/16 06:00 MHDA- 2020/11/16 06:01 CRDT- 2020/11/15 20:21 PHST- 2020/08/18 00:00 [received] PHST- 2020/10/28 00:00 [revised] PHST- 2020/10/29 00:00 [accepted] PHST- 2020/11/16 06:00 [pubmed] PHST- 2020/11/16 06:01 [medline] PHST- 2020/11/15 20:21 [entrez] AID - S0021-9797(20)31475-2 [pii] AID - 10.1016/j.jcis.2020.10.135 [doi] PST - ppublish SO - J Colloid Interface Sci. 2021 Mar 15;586:655-662. doi: 10.1016/j.jcis.2020.10.135. Epub 2020 Nov 3.