PMID- 33215819
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20201123
LR  - 20201123
IS  - 1096-9888 (Electronic)
IS  - 1076-5174 (Linking)
VI  - 55
IP  - 12
DP  - 2020 Dec
TI  - Applicability of purge and trap gas chromatography- mass spectrometry method for 
      sensitive analytical detection of naphthalene and its derivatives in waters.
PG  - e4672
LID - 10.1002/jms.4672 [doi]
AB  - Nowadays, a wide variety of chemicals has emerged because of increasing 
      industrial and human activities. Thus, environmental chemistry laboratories 
      performing analytical measurements need rapid and sensitive methods more than 
      ever to get reliable quantitative data. For this purpose, a purge and trap gas 
      chromatography-mass spectrometry (GC-MS) method was developed and validated for 
      the rapid, simple, and sensitive determination of the presence of naphthalene and 
      its derivatives in waters. The method validation was based on specificity, 
      calibration curve linearity, limit of detection (LOD) and limit of quantification 
      (LOQ), accuracy (recovery), precision, matrix effects (MEs), and measurement 
      uncertainty. This method showed excellent linearity from 1.00 to 40.00 mug/L 
      except naphthalene (0.50-40.00 mug/L) because the correlation coefficients were 
      higher than 0.997 for all analytes. The LOQ values varied from 0.312 to 0.746 
      mug/L, and the LOD values changed from 0.094 to 0.224 mug/L with relative standard 
      deviations (RSDs) for all compounds below 10% (3.12-7.46), respectively. 
      Recoveries ranged from 81.9% to 95.6%, and repeatability and reproducibility (in 
      terms of RSD for six measurements) were lower than 10% in all cases. F test was 
      subjected on the related data at 95% confidence level, and no statistically 
      significant difference was observed. There was no critical ME (recovery varied 
      from 80% to 110% in all matrices). In measurement uncertainty, the expanded 
      uncertainties of each analyte were changed in the range of 0.39-0.52 mug/L, and 
      the calibration curve and repeatability had dominant effects on the combined 
      uncertainty. The application to real samples was successfully assessed by the 
      developed method. These results indicate that the developed method is suitable 
      for the determination of naphthalene and its derivatives in waters.
CI  - (c) 2020 John Wiley & Sons, Ltd.
FAU - Guzel, Baris
AU  - Guzel B
AUID- ORCID: 0000-0002-6709-2339
AD  - Environment and Cleaner Production Institute, TUBITAK Marmara Research Center, 
      Kocaeli, Turkey.
FAU - Canli, Oltan
AU  - Canli O
AUID- ORCID: 0000-0002-2652-844X
AD  - Environment and Cleaner Production Institute, TUBITAK Marmara Research Center, 
      Kocaeli, Turkey.
LA  - eng
PT  - Journal Article
PL  - England
TA  - J Mass Spectrom
JT  - Journal of mass spectrometry : JMS
JID - 9504818
SB  - IM
OTO - NOTNLM
OT  - gas chromatography
OT  - naphthalene
OT  - purge and trap
OT  - validation
OT  - water
EDAT- 2020/11/21 06:00
MHDA- 2020/11/21 06:01
CRDT- 2020/11/20 08:41
PHST- 2020/08/23 00:00 [received]
PHST- 2020/10/12 00:00 [revised]
PHST- 2020/10/14 00:00 [accepted]
PHST- 2020/11/20 08:41 [entrez]
PHST- 2020/11/21 06:00 [pubmed]
PHST- 2020/11/21 06:01 [medline]
AID - 10.1002/jms.4672 [doi]
PST - ppublish
SO  - J Mass Spectrom. 2020 Dec;55(12):e4672. doi: 10.1002/jms.4672.