PMID- 33265957 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201226 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 12 IP - 12 DP - 2020 Nov 30 TI - Thermally Conductive Polyethylene/Expanded Graphite Composites as Heat Transfer Surface: Mechanical, Thermo-Physical and Surface Behavior. LID - 10.3390/polym12122863 [doi] LID - 2863 AB - Composites of high-density polyethylene (HDPE) and expanded graphite (EG) are prepared for heat exchangers in multi-effect distillation (MED) desalination. At 50 wt.% EG loading, the thermal conductivity of HDPE was increased by 372%. Moreover, the surface wettability of the HDPE/EG composite was enhanced by corona and RF plasma treatment as demonstrated by the increase in surface free energy from 28.5 mJ/m(2) for untreated HDPE/EG to 55.5 and 54.5 mJ/m(2) for HDPE/EG treated by corona and RF plasma, respectively. This enhanced surface wettability was retained over a long time with only a 9% and 18% decrease in RF and corona plasma-treated samples' surface energy after two months. The viscoelastic moduli and the complex viscosity profiles indicated that EG content dictates the optimum processing technique. At loading below 30 wt.%, the extrusion process is preferred, while above 30 wt.% loading, injection molding is preferred. The plasma treatment also improved the HDPE/EG composite overall heat transfer coefficient with an overall heat transfer coefficient of the composite reaching about 98% that of stainless steel. Moreover, the plasma-treated composite exhibited superior resistance to crystallization fouling in both CaSO(4) solution and artificial seawater compared to untreated composites and stainless-steel surfaces. FAU - Sobolciak, Patrik AU - Sobolciak P AD - Center for Advanced Materials, Qatar University, P.O. Box 2713 Doha, Qatar. FAU - Abdulgader, Asma AU - Abdulgader A AD - Center for Advanced Materials, Qatar University, P.O. Box 2713 Doha, Qatar. FAU - Mrlik, Miroslav AU - Mrlik M AUID- ORCID: 0000-0001-6203-6795 AD - Centre of Polymer Systems, University Institute, Tomas Bata University in Zlin, Trida T. Bati 5678, 76001 Zlin, Czech Republic. FAU - Popelka, Anton AU - Popelka A AD - Center for Advanced Materials, Qatar University, P.O. Box 2713 Doha, Qatar. FAU - A Abdala, Ahmed AU - A Abdala A AD - Chemical Engineering Program, Texas A&M University at Qatar, P.O. Box 23874 Doha, Qatar. FAU - A Aboukhlewa, Abdelnasser AU - A Aboukhlewa A AD - Qatar Environment and Energy Research Institute, HBKU, P.O. Box 5825 Doha, Qatar. FAU - Karkri, Mustapha AU - Karkri M AUID- ORCID: 0000-0002-7376-0508 AD - CERTES, Universite Paris-Est Creteil Val de Marne, 94000 Paris, France. FAU - Kiepfer, Hendrik AU - Kiepfer H AUID- ORCID: 0000-0003-1552-0386 AD - Chair of Separation Science and Technology, P.O. Box 3049 TU Kaiserslautern, 67653 Kaiserslautern, Germany. FAU - Bart, Hans-Jorg AU - Bart HJ AD - Chair of Separation Science and Technology, P.O. Box 3049 TU Kaiserslautern, 67653 Kaiserslautern, Germany. FAU - Krupa, Igor AU - Krupa I AD - Center for Advanced Materials, Qatar University, P.O. Box 2713 Doha, Qatar. LA - eng GR - NPRP10-0205-170349/Qatar National Research Fund/ PT - Journal Article DEP - 20201130 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC7760837 OTO - NOTNLM OT - expanded graphite OT - high density polyethylene OT - multi-effect distillation OT - plasma treatment OT - polymeric composites OT - scaling COIS- The authors declare no conflict of interest. EDAT- 2020/12/04 06:00 MHDA- 2020/12/04 06:01 PMCR- 2020/11/30 CRDT- 2020/12/03 01:05 PHST- 2020/11/05 00:00 [received] PHST- 2020/11/22 00:00 [revised] PHST- 2020/11/23 00:00 [accepted] PHST- 2020/12/03 01:05 [entrez] PHST- 2020/12/04 06:00 [pubmed] PHST- 2020/12/04 06:01 [medline] PHST- 2020/11/30 00:00 [pmc-release] AID - polym12122863 [pii] AID - polymers-12-02863 [pii] AID - 10.3390/polym12122863 [doi] PST - epublish SO - Polymers (Basel). 2020 Nov 30;12(12):2863. doi: 10.3390/polym12122863.