PMID- 33304017 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20210110 IS - 0140-7007 (Print) IS - 1879-2081 (Electronic) IS - 0140-7007 (Linking) VI - 104 DP - 2019 TI - The hunt for nonflammable refrigerant blends to replace R-134a. LID - 10.1016/j.ijrefrig.2019.05.035 [doi] AB - We investigated refrigerant blends as possible low GWP (global warming potential) alternatives for R-134a in an air-conditioning application. We carried out an extensive screening of the binary, ternary, and four-component blends possible among a list of 13 pure refrigerants comprising four hydrofluoroolefins (HFOs), eight hydrofluorocarbons (HFCs), and carbon dioxide. The screening was based on a simplified cycle model, but with the inclusion of pressure drops in the evaporator and condenser. The metrics for the evaluation were nonflammability, low GWP, high COP (coefficient of performance), and a volumetric capacity similar to the R-134a baseline system. While no mixture was ideal in all regards, we identified 16 binary and ternary blends that were nonflammable (based on a new estimation method) and with COP and capacity similar to the R-134a baseline; the tradeoff, however, was a reduction in GWP of, at most, 54% compared to R-134a. An additional seven blends that were estimated to be "marginally flammable" (ASHRAE Standard 34 classification of A2L) were identified with GWP reductions of as much as 99%. These 23 "best" blends were then simulated in a more detailed cycle model. FAU - Bell, Ian H AU - Bell IH AD - Applied Chemicals and Materials Division, National Institute of Standards and Technology, Boulder, CO, 80305, USA. FAU - Domanski, Piotr A AU - Domanski PA AD - Energy and Environment Division, National Institute of Standards and Technology, Gaithersburg, MD, 20899, USA. FAU - McLinden, Mark O AU - McLinden MO AD - Applied Chemicals and Materials Division, National Institute of Standards and Technology, Boulder, CO, 80305, USA. FAU - Linteris, Gregory T AU - Linteris GT AD - Energy and Environment Division, National Institute of Standards and Technology, Gaithersburg, MD, 20899, USA. LA - eng SI - figshare/10.6084/m9.figshare.8171342 GR - 9999-NIST/ImNIST/Intramural NIST DOC/United States PT - Journal Article PL - Netherlands TA - Int J Refrig JT - Revue internationale du froid JID - 101544778 PMC - PMC7724586 MID - NIHMS1573019 OTO - NOTNLM OT - alternatives to R-134a OT - cycle efficiency OT - flammability OT - refrigerant blends EDAT- 2019/01/01 00:00 MHDA- 2019/01/01 00:01 PMCR- 2020/12/09 CRDT- 2020/12/11 06:00 PHST- 2020/12/11 06:00 [entrez] PHST- 2019/01/01 00:00 [pubmed] PHST- 2019/01/01 00:01 [medline] PHST- 2020/12/09 00:00 [pmc-release] AID - 10.1016/j.ijrefrig.2019.05.035 [doi] PST - ppublish SO - Int J Refrig. 2019;104:10.1016/j.ijrefrig.2019.05.035. doi: 10.1016/j.ijrefrig.2019.05.035.