PMID- 33310318 OWN - NLM STAT- MEDLINE DCOM- 20210531 LR - 20210531 IS - 1873-3336 (Electronic) IS - 0304-3894 (Linking) VI - 406 DP - 2021 Mar 15 TI - Isolation of biosynthetic crystals by microbially induced calcium carbonate precipitation and their utilization for fluoride removal from groundwater. PG - 124748 LID - S0304-3894(20)32738-2 [pii] LID - 10.1016/j.jhazmat.2020.124748 [doi] AB - Biosynthetic crystals (BC) were prepared through microbially induced calcium carbonate precipitation (MICP) for fluoride (F(-)) removal from the groundwater. Batch experiments were conducted to evaluate the fluoride adsorption capacity and the impacts of critical factors (organic matter, pH, initial fluoride concentration and BC dosage) on defluorination efficiency of BC. The maximum adsorption amount and defluorination efficiency were recorded as 5.10 mg g(-1) and 98.24%, respectively. The adsorption kinetics and isotherms studies showed that pseudo-second-order kinetic model and Freundlich isotherm model were best fitting to the reaction. Adsorption thermodynamic parameters indicated a spontaneous, endothermic and thermodynamically favorable adsorption process. Moreover, the mechanism of F(-) removal by BC was further analyzed by SEM, XPS, XRD and FTIR. The method can cope with the problem of applying the external organic substances in MICP, and avoid the microbial safety risk in the effluent. As an economically and environmentally friendly adsorbent, BC can be used for F(-) removal from groundwater. CI - Copyright (c) 2020 Elsevier B.V. All rights reserved. FAU - Wang, Zhao AU - Wang Z AD - School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China. FAU - Su, Junfeng AU - Su J AD - School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; State Key Laboratory of Green Building in West China, Xi'an University of Architecture and Technology, Xi'an 710055, China. Electronic address: sjf1977518@sina.com. FAU - Hu, Xiaofen AU - Hu X AD - School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China. FAU - Ali, Amjad AU - Ali A AD - School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China. Electronic address: amjadali@aup.edu.pk. FAU - Wu, Zizhen AU - Wu Z AD - School of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China; Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20201203 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Water Pollutants, Chemical) RN - H0G9379FGK (Calcium Carbonate) RN - Q80VPU408O (Fluorides) SB - IM MH - Adsorption MH - Calcium Carbonate MH - Fluorides MH - *Groundwater MH - Hydrogen-Ion Concentration MH - Kinetics MH - Thermodynamics MH - *Water Pollutants, Chemical/analysis MH - *Water Purification OTO - NOTNLM OT - Adsorption mechanism OT - Biosynthetic crystal OT - Calcium carbonate precipitation OT - Fluoride OT - Groundwater EDAT- 2020/12/15 06:00 MHDA- 2021/06/01 06:00 CRDT- 2020/12/14 10:28 PHST- 2020/09/18 00:00 [received] PHST- 2020/11/29 00:00 [revised] PHST- 2020/11/30 00:00 [accepted] PHST- 2020/12/15 06:00 [pubmed] PHST- 2021/06/01 06:00 [medline] PHST- 2020/12/14 10:28 [entrez] AID - S0304-3894(20)32738-2 [pii] AID - 10.1016/j.jhazmat.2020.124748 [doi] PST - ppublish SO - J Hazard Mater. 2021 Mar 15;406:124748. doi: 10.1016/j.jhazmat.2020.124748. Epub 2020 Dec 3.